methyl phenyldithioacetate

Base Information

• Chemical Name: methyl phenyldithioacetate
• CAS No.: 2168-85-6
• Molecular Formula: C₉H₁₀S₂
• Molecular Weight: 182.31
• Mol file: 2168-85-6.mol

Synonyms:methyl phenyldithioacetate

Chemical Property of methyl phenyldithioacetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methyl phenyldithioacetate

There total 17 articles about methyl phenyldithioacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

(S,S)-dimethyl trithiocarbonate (2314-48-9) + toluene (108-88-3,15644-74-3,16713-13-6) → methyl phenyldithioacetate (2168-85-6)

Guidance literature:

With sodium hydride; dimethyl sulfoxide;

Reference yield: 65.0%

phenylacetic acid (103-82-2) + 2,4-bis(methylthio)-1,3-dithia-2,4-diphosphetane-2,4-disulfide (82737-61-9) → methyl phenyldithioacetate (2168-85-6)

Guidance literature:

In chlorobenzene; at 132 ℃;

Reference yield: 65.0%

O,O-dimethyl phosphorodithioic acid (756-80-9) + phenylacetyl chloride (103-80-0) → methyl phenyldithioacetate (2168-85-6)

Guidance literature:

at 130 ℃; for 3.5h;

upstream raw materials:

acetophenone

methyl iodide

phenyldithioacetic acid

dimethyl sulfate

Downstream raw materials:

3,3-diethoxy-2-(2-phenyl-thioacetylamino)-propionic acid

(CO)3FeC(CH₂(C₆H₅))S(CH₃)SFe(CO)3

(4-methyl-6-phenyl-1⁽³⁾H-thieno[3,4-d]imidazol-2-yl)-phenyl-methanol

2-(hydroxy-phenyl-methyl)-6-phenyl-1⁽³⁾H-thieno[3,4-d]imidazole-4-carboxylic acid

Refernces

• 1、 Bulpin, Andrew,Masson, Serge. "The Addition of Thiols to Phosphonodithioformates: Reactivity of Phosphorylated Dithioacetal Disulfides". . p. 4507 - 4512. Retrieved 2007/10/02.
• 2、 Lee, Ving J.,Curran, William V.,Fields, Thomas F.,Learn, Keith. "1,2,3-Thiadiazoles. I. Synthesis of Sodium (or Potassium) 1,2,3-Thiadiazole-4-thiolates via Thiocarbazonate Esters and N-Acylthiohydrazonate Esters". . p. 1873 - 1891. Retrieved 2007/10/02.