(2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl₂

Base Information

• Chemical Name: (2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl₂
• CAS No.: 349545-05-7
• Molecular Formula: C₂₉H₄₁Cl₂GaN₂
• Molecular Weight: 558.287
• Mol file: 349545-05-7.mol

Synonyms:(2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl₂

Chemical Property of (2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl₂

There total 6 articles about (2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

Dipp2nacnacLi*Et2O (334719-92-5,872515-36-1) + Gallium trichloride (13450-90-3) → (2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl2 (349545-05-7)

Guidance literature:

In toluene; byproducts: LiCl; toluene soln. of ligand was added dropwise to GaCl3 at 0°C with stirring under inert atm., warmed to room temp. overnight; solvent was removed under reduced pressure, extd. with hexane, filtered,concd., cooled; elem. anal.;

DOI:10.1021/ic001311d

Reference yield: 24.0%

[Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)] (317322-17-1) + C20H31BiCl3N → (2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl2 (349545-05-7) + C49H72BiClGaN3

Guidance literature:

In toluene; at -100 - -30 ℃; for 3h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1021/acs.inorgchem.1c03279

Reference yield: 17.0%

C58H82Cl3Ga2N4Sb + C9H18N2 → (2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl2 (349545-05-7) + C67H99Cl2Ga2N6Sb2

Guidance literature:

C₅₈H₈₂Cl₃Ga₂N₄Sb; C₉H₁₈N₂; In benzene; at 0 ℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox;

at 20 ℃; for 24h; Overall yield = 16 percent; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1002/ejic.202100960

upstream raw materials:

Dipp₂nacnacLi*Et₂O

Gallium trichloride

Li(2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)(tetrahydtofuran)

[Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)]

Downstream raw materials:

(2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl(OSO₂CF₃)

(2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl(OSiMe₃)

(2,6-iPr₂C₆H₃)NC(Me)CHC(Me)N(2,6-iPr₂C₆H₃)Ga(OH)2

[(CH(C(CH₃)N(C₆H₃(CH(CH₃)2)2))2)Ga(NH₂)2]