Technology Process of dimesitylfluoro(trichloro)germane
There total 1 articles about dimesitylfluoro(trichloro)germane which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
n-BuLi;
In
tetrahydrofuran; hexane; chloroform;
byproducts: LiF; (Ar); std. Schlenk technique; soln. of BuLi in hexane was added to mixt.of Ge compd. and CHCl3 (1 equiv.) in THF at -110°C; slowly warme d to room temp.; stirred for 4 h; filtered; solvent removed (vac.); crystd. (pentane); elem. anal.;
DOI:10.1021/om061188j
- Guidance literature:
-
With
t-BuLi;
In
tetrahydrofuran; methanol; hexane;
(Ar); std. Schlenk technique; soln. of BuLi in hexane was added to soln.of Ge compd. in THF at -110°C; stirred at -80°C for 30 mi n; MeOH was added; slowly warmed to room temp. within 2 h; filtered; concd. (vac.); cooled in pentane at -20°C;
DOI:10.1021/om061188j
- Guidance literature:
-
With
t-BuLi;
In
tetrahydrofuran; hexane;
byproducts: LiF; (Ar); std. Schlenk technique; soln. of BuLi in hexane was added to soln.of Ge compd. in THF at -110°C; slowly warmed to room temp. withi n 2 h; filtered; solvent removed (vac.); Et2O added; cooled to -20°C; elem. anal.;
DOI:10.1021/om061188j
