C₅₆H₅₆N₄O₁₄

Base Information

• Chemical Name: C₅₆H₅₆N₄O₁₄
• CAS No.: 1287768-41-5
• Molecular Formula: C₅₆H₅₆N₄O₁₄
• Molecular Weight: 1009.08
• Mol file: 1287768-41-5.mol

Synonyms:C₅₆H₅₆N₄O₁₄

Chemical Property of C₅₆H₅₆N₄O₁₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅₆H₅₆N₄O₁₄

There total 22 articles about C₅₆H₅₆N₄O₁₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzyl bromide (100-39-0) → C56H56N4O14 (1287768-41-5)

Guidance literature:

Multi-step reaction with 5 steps

1: barium(II) hydroxide; barium(II) oxide / N,N-dimethyl-formamide / 0 - 20 °C

2: triethylsilane; boron trifluoride diethyl etherate / dichloromethane / 1 h / 0 °C

3: barium(II) hydroxide; barium(II) oxide / N,N-dimethyl-formamide / 0 - 20 °C

4: copper(l) iodide; N-ethyl-N,N-diisopropylamine / acetonitrile / 2 h / 20 °C

5: trifluorormethanesulfonic acid / dichloromethane / 20 °C / Molecular sieve

With triethylsilane; copper(l) iodide; trifluorormethanesulfonic acid; boron trifluoride diethyl etherate; N-ethyl-N,N-diisopropylamine; barium(II) hydroxide; barium(II) oxide; In dichloromethane; N,N-dimethyl-formamide; acetonitrile;

DOI:10.1021/jo200076z

Reference yield:

phenyl 2,3-di-O-benzoyl-4,6-O-p-methoxy-benzylidene-1-thio-β-D-glucopyranoside (1287768-28-8) → C56H56N4O14 (1287768-41-5)

Guidance literature:

Multi-step reaction with 7 steps

1.1: triethylsilane; phenylborondichloride / dichloromethane / 0.5 h / -78 °C / Molecular sieve; Inert atmosphere

2.1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane; water / 20 °C

3.1: caesium carbonate / N,N-dimethyl-formamide / 0 °C

3.2: 1 h / 0 °C

4.1: N-iodo-succinimide; acetic acid / dichloromethane / 20 °C

5.1: trimethylsilylazide; tin(IV) chloride / dichloromethane / 3 h / 20 °C

6.1: copper(l) iodide; N-ethyl-N,N-diisopropylamine / acetonitrile / 2 h / 20 °C

7.1: trifluorormethanesulfonic acid / dichloromethane / 20 °C / Molecular sieve

With triethylsilane; N-iodo-succinimide; copper(l) iodide; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; trifluorormethanesulfonic acid; [bis(acetoxy)iodo]benzene; trimethylsilylazide; phenylborondichloride; tin(IV) chloride; caesium carbonate; acetic acid; N-ethyl-N,N-diisopropylamine; In dichloromethane; water; N,N-dimethyl-formamide; acetonitrile;

DOI:10.1021/jo200076z

Reference yield:

C34H30O9S (1287768-50-6) → C56H56N4O14 (1287768-41-5)

Guidance literature:

Multi-step reaction with 5 steps

1.1: caesium carbonate / N,N-dimethyl-formamide / 0 °C

1.2: 1 h / 0 °C

2.1: N-iodo-succinimide; acetic acid / dichloromethane / 20 °C

3.1: trimethylsilylazide; tin(IV) chloride / dichloromethane / 3 h / 20 °C

4.1: copper(l) iodide; N-ethyl-N,N-diisopropylamine / acetonitrile / 2 h / 20 °C

5.1: trifluorormethanesulfonic acid / dichloromethane / 20 °C / Molecular sieve

With N-iodo-succinimide; copper(l) iodide; trifluorormethanesulfonic acid; trimethylsilylazide; tin(IV) chloride; caesium carbonate; acetic acid; N-ethyl-N,N-diisopropylamine; In dichloromethane; N,N-dimethyl-formamide; acetonitrile;

DOI:10.1021/jo200076z

upstream raw materials:

phenyl 2,3-di-O-benzoyl-4,6-O-p-methoxy-benzylidene-1-thio-β-D-glucopyranoside

phenyl 2,3-di-O-benzoyl-4-O-p-methoxybenzyl-1-thio-β-D-glucopyranoside

C₃₄H₃₀O₉S

methyl phenyl 2,3-di-O-benzoyl-4-O-p-methoxybenzyl-1-thio-β-D-glucuronate

Downstream raw materials:

C₉₂H₉₅N₁₁O₂₉