DECANE,2,9-DIMETHYL-

Base Information

• Chemical Name: DECANE,2,9-DIMETHYL-
• CAS No.: 1002-17-1
• Molecular Formula: C12H26
• Molecular Weight: 170.338
• Hs Code.: 2901100000
• Mol file: 1002-17-1.mol

Synonyms:2,9-Dimethyldecane

Chemical Property of DECANE,2,9-DIMETHYL-

Chemical Property:

• Melting Point: -50.8°C (estimate)
• Refractive Index: 1.4166
• Boiling Point: 204°C
• PSA: 0.00000
• Density: 0.7404
• LogP: 4.63900

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of DECANE,2,9-DIMETHYL-

There total 3 articles about DECANE,2,9-DIMETHYL- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

1 ,6-dibromohexane (629-03-8) + isopropylmagnesium bromide (920-39-8) → 2,9-dimethyl-decane (1002-17-1) + 1-bromo-7-methyl-octane (54088-99-2)

Guidance literature:

With copper(I) bromide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; for 4h; Product distribution; Heating; Grignard reagent added dropwise to the other reaction partners;

DOI:10.1246/bcsj.59.2035

Reference yield: 34.0%

oxirane (75-21-8,99932-75-9) + 1-bromo-5-methylpentane (626-88-0) → 2,9-dimethyl-decane (1002-17-1) + 6-methylheptanol (1653-40-3)

Guidance literature:

1-bromo-5-methylpentane; With magnesium; In diethyl ether;

oxirane; In diethyl ether; at 20 ℃; Title compound not separated from byproducts;

DOI:10.1246/bcsj.75.111

Reference yield:

3-methylbutyric acid (503-74-2) + 5-methylhexanoic acid (628-46-6) → 2,5-dimethylhexane (592-13-2) + 2,7-dimethyloctane (1072-16-8) + 2,9-dimethyl-decane (1002-17-1)

Guidance literature:

With Ti_0.5Ru_0.5O₂; triethylamine; In methanol; at 0 ℃; Reagent/catalyst; Electrochemical reaction;

DOI:10.1039/c8gc03745k

upstream raw materials:

1 ,6-dibromohexane

isopropylmagnesium bromide

oxirane

1-bromo-5-methylpentane

Refernces

• 1、 Tai, Akira,Syouno, Emi,Tanaka, Kazuki,Fujita, Morifumi,Sugimura, Takashi,Higashiura, Yasutomo,Kakizaki, Masashi,Hara, Hideho,Naito, Tikahiko. "Regio- and stereochemical study of sex pheromone of pine sawfly; Diprion nipponica". . p. 111 - 121. Retrieved 2007/10/03.