(2-Aminoethyl)carbamic acid

Base Information

• Chemical Name: (2-Aminoethyl)carbamic acid
• CAS No.: 109-58-0
• Deprecated CAS: 24464-90-2
• Molecular Formula: C3H8 N2 O2
• Molecular Weight: 104.109
• Hs Code.: 2924199090
• European Community (EC) Number: 203-684-0
• UNII: 5823XF90GJ
• DSSTox Substance ID: DTXSID0059374
• Nikkaji Number: J43.030G
• Wikidata: Q27261541
• Mol file: 109-58-0.mol

Synonyms:(2-AMINOETHYL)CARBAMIC ACID;109-58-0;Ethylenediamine carbamate;2-aminoethylcarbamic acid;Carbamic acid, (2-aminoethyl)-;Carbamic acid, compd with ethylenediamine;UNII-5823XF90GJ;Carbamic acid, compd with 1,2-ethanediamine;HSDB 2573;5823XF90GJ;Carbamic acid, N-(2-aminoethyl)-;EINECS 203-684-0;(2-Aminoethyl)-carbamic acid;carboxyethylenediamine;2-Aminoethyl Carbamic Acid;SCHEMBL322077;DTXSID0059374;N-(CARBOXY)ETHYLENEDIAMINE;AKOS006339198;GP- 212;(2-AMINOETHYL)CARBAMIC ACID [HSDB];Q27261541;24464-90-2

Chemical Property of (2-Aminoethyl)carbamic acid

Chemical Property:

• Refractive Index: 1.49
• PKA: 4.67±0.41(Predicted)
• PSA: 75.35000
• Density: 1.222g/cm³
• LogP: 0.30390
• XLogP3: -3.6
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 104.058577502
• Heavy Atom Count: 7
• Complexity: 64

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Carbamic Acid Esters
• Canonical SMILES: C(CNC(=O)O)N

Technology Process of (2-Aminoethyl)carbamic acid

There total 6 articles about (2-Aminoethyl)carbamic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

carbon dioxide (124-38-9,18923-20-1) + ethylenediamine (107-15-3,85404-18-8) → N-β-aminoethylcarbamic acid (109-58-0)

Guidance literature:

at 50 ℃; for 5h; under 22502.3 Torr; Solvent;

Reference yield: 31.7%

carbon monoxide (201230-82-2) + ethylenediamine (107-15-3,85404-18-8) → 2-imidazoline (504-75-6) + imidazolidone (120-93-4) + N-β-aminoethylcarbamic acid (109-58-0)

Guidance literature:

With tetracarbonyl nickel; In ethanol; at 160 ℃; for 18h;

DOI:10.1016/S0022-328X(00)83034-X

Reference yield:

carbon dioxide (124-38-9,18923-20-1) + ethylenediamine (107-15-3,85404-18-8) → N-β-aminoethylcarbamic acid (109-58-0) + 2CH2O3*C2H8N2 + (2-Carboxyamino-ethyl)-carbamic acid; compound with ethane-1,2-diamine (82357-56-0)

Guidance literature:

With water; In diethyl ether; at 20 ℃;

DOI:10.1515/znb-2011-0209

upstream raw materials:

methylammonium carbonate

ethylenediamine

carbon dioxide

carbon monoxide

Downstream raw materials:

1,2-propylene cyclic carbonate

ethylenediamine

[1,3]-dioxolan-2-one

N,N'-bis(4-chlorobenzylidene)ethane-1,2-diamine

Refernces

• 1、 Rezende, Marcos Caroli,Dall'Oglio, Evandro Luiz,Zucco, Cesar. "Puzzling formation of bisimidazole derivatives from hexachloroacetone and diamines". . p. 5265 - 5268. Retrieved 1996.
• 2、 Katchalski et al.. "-". . p. 1829. Retrieved 1951.
• 3、 -. "PREPARING METHOD OF SOLID CARBAMIC ACID DERIVATIVES". Paragraph 0042-0046. . Retrieved 2014/03/24.