(E)-1-Trimethylsilyl-1,3-butadiene

Base Information

Chemical Name:(E)-1-Trimethylsilyl-1,3-butadiene
CAS No.:71504-26-2
Molecular Formula:C₇H₁₄Si
Molecular Weight:126.274
Hs Code.:
DSSTox Substance ID:DTXSID80437097

Synonyms:71504-26-2;(E)-1-TRIMETHYLSILYL-1,3-BUTADIENE;1-trimethylsilylbutadiene;DTXSID80437097

Suppliers and Price of (E)-1-Trimethylsilyl-1,3-butadiene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of (E)-1-Trimethylsilyl-1,3-butadiene

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:2
Exact Mass:126.086476981
Heavy Atom Count:8
Complexity:95.4

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)C=CC=C
Physical properties bp 110–115 °C, 70–74 °C/210 mmHg.
Uses As as useful reagent, (E)-1-Trimethylsilyl-1,3-butadiene is used as a diene for Diels–Alder reactions, creating allylsilanes that can be converted to a variety of functionalized cyclohexenes with a shift of the double bond from its original position in the cycloaddition; synthesis of a chiral allylborane; synthesis of allylsilanes and trienes

Technology Process of (E)-1-Trimethylsilyl-1,3-butadiene

There total 5 articles about (E)-1-Trimethylsilyl-1,3-butadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 86593-81-9
((1S,3R,7R)-4,4-Dioxo-4λ⁶-thia-tricyclo[5.2.1.0^2,6]dec-8-en-3-yl)-trimethyl-silane

: 71504-26-2
(E)-1-(trimethylsilyl)buta-1,3-diene

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

Guidance literature:: at 650 ℃; under 0.01 Torr;

Reference yield:

: 71404-34-7
(E)-1,4-bis(trimethylsilyl)but-3-en-2-ol

: 107-46-0
Hexamethyldisiloxane

: 71504-26-2
(E)-1-(trimethylsilyl)buta-1,3-diene

Guidance literature:: With toluene-4-sulfonic acid; In diethyl ether; for 1h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; Ambient temperature;
DOI:10.1039/P19810002415

Reference yield:

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 61518-50-1
1,3-bis(trimethylsilyl)prop-1-enyl-lithium

: 107-46-0
Hexamethyldisiloxane

: 71504-26-2
(E)-1-(trimethylsilyl)buta-1,3-diene

Guidance literature:: In tetrahydrofuran; for 1h; Yield given. Title compound not separated from byproducts; Ambient temperature;
DOI:10.1039/P19810002415