1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-myo-inositol 3,4,5-tris(dibenzyl phosphate)

Base Information

Chemical Name:1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-myo-inositol 3,4,5-tris(dibenzyl phosphate)
CAS No.:496808-74-3
Molecular Formula:C₆₈H₇₇O₁₇P₃Si
Molecular Weight:1287.36
Hs Code.:

Synonyms:1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-myo-inositol 3,4,5-tris(dibenzyl phosphate)

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Chemical Property of 1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-myo-inositol 3,4,5-tris(dibenzyl phosphate)

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Technology Process of 1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-myo-inositol 3,4,5-tris(dibenzyl phosphate)

There total 8 articles about 1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-myo-inositol 3,4,5-tris(dibenzyl phosphate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 108549-23-1
Dibenzyl N,N-diisopropylphosphoramidite

: 142534-58-5
1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-myo-inositol

: 496808-74-3
1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-myo-inositol 3,4,5-tris(dibenzyl phosphate)

Guidance literature:: Dibenzyl N,N-diisopropylphosphoramidite; 1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-myo-inositol; With 1H-tetrazole; In acetonitrile; for 6h;

With 3-chloro-benzenecarboperoxoic acid; In chloroform; acetonitrile; at -20 ℃; Further stages.;
DOI:10.1021/jo0206418

Reference yield:

: 331679-26-6
2,3-O-(D-1,7,7-trimethylbicyclo[2.2.1]hept-6-ylidene)-D-myo-inositol

: 496808-74-3
1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-myo-inositol 3,4,5-tris(dibenzyl phosphate)

Guidance literature:: Multi-step reaction with 6 steps

1.1: 88 percent / imidazole

2.1: 90 percent / HSCH₂CH₂OH; BF₃*Et₂O

3.1: 92 percent / pyridine / -40 °C

4.1: 75 percent / diisopropylethylamine / dimethylformamide

5.1: 96 percent / methylamine / CHCl₃; ethanol / 48 h / 50 °C

6.1: tetrazole / acetonitrile / 6 h

6.2: 84 percent / 3-chloroperoxybenzoic acid / acetonitrile; CHCl₃ / -20 °C

With pyridine; 1H-imidazole; 1H-tetrazole; boron trifluoride diethyl etherate; N-ethyl-N,N-diisopropylamine; methylamine; 2-hydroxyethanethiol; In ethanol; chloroform; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo0206418

Reference yield:

: 142534-54-1
1D-1-O-(tert-butyldiphenylsilyl)-myo-inositol

: 496808-74-3
1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-myo-inositol 3,4,5-tris(dibenzyl phosphate)

Guidance literature:: Multi-step reaction with 4 steps

1.1: 92 percent / pyridine / -40 °C

2.1: 75 percent / diisopropylethylamine / dimethylformamide

3.1: 96 percent / methylamine / CHCl₃; ethanol / 48 h / 50 °C

4.1: tetrazole / acetonitrile / 6 h

4.2: 84 percent / 3-chloroperoxybenzoic acid / acetonitrile; CHCl₃ / -20 °C

With pyridine; 1H-tetrazole; N-ethyl-N,N-diisopropylamine; methylamine; In ethanol; chloroform; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo0206418