6-[1-(p-methoxybenzyloxy)-2-propyl]-2-(phenylseleno)methyl-4-isopropenyl-[1,3]-dioxane

Base Information

Chemical Name:6-[1-(p-methoxybenzyloxy)-2-propyl]-2-(phenylseleno)methyl-4-isopropenyl-[1,3]-dioxane
CAS No.:261968-14-3
Molecular Formula:C₂₆H₃₄O₄Se
Molecular Weight:489.514
Hs Code.:

Synonyms:6-[1-(p-methoxybenzyloxy)-2-propyl]-2-(phenylseleno)methyl-4-isopropenyl-[1,3]-dioxane

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Chemical Property of 6-[1-(p-methoxybenzyloxy)-2-propyl]-2-(phenylseleno)methyl-4-isopropenyl-[1,3]-dioxane

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Technology Process of 6-[1-(p-methoxybenzyloxy)-2-propyl]-2-(phenylseleno)methyl-4-isopropenyl-[1,3]-dioxane

There total 9 articles about 6-[1-(p-methoxybenzyloxy)-2-propyl]-2-(phenylseleno)methyl-4-isopropenyl-[1,3]-dioxane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 71338-47-1
2-phenylselenoacetaldehyde diethylacetal

: 373645-63-7
1-(p-methoxybenzyloxy)-3,5-dihydroxy-2,4,6-trimethyl-6-heptene

: 261968-14-3
6-[1-(p-methoxybenzyloxy)-2-propyl]-2-(phenylseleno)methyl-4-isopropenyl-[1,3]-dioxane

Guidance literature:: With pyridinium p-toluenesulfonate; In toluene; for 4h; Heating;
DOI:10.1021/ja011211m

Reference yield:

: 182193-69-7
(S)-1-(p-methoxybenzyloxy)-2-methylpentan-3-one

: 261968-14-3
6-[1-(p-methoxybenzyloxy)-2-propyl]-2-(phenylseleno)methyl-4-isopropenyl-[1,3]-dioxane

Guidance literature:: Multi-step reaction with 5 steps

1.1: Et₃N / diethyl ether / 1 h / 0 °C

2.1: diethyl ether / 21 h / -20 °C

2.2: 95 percent / 30percent aq. H₂O₂ / methanol / 0 - 20 °C / pH 7

3.1: 96 percent / SmI₂ / tetrahydrofuran / 1.5 h / -10 °C

4.1: 97 percent / K₂CO₃ / methanol; H₂O / 5 h / 20 °C

5.1: 94 percent / PPTS / toluene / 4 h / Heating

With samarium diiodide; pyridinium p-toluenesulfonate; potassium carbonate; triethylamine; In tetrahydrofuran; methanol; diethyl ether; water; toluene; 3.1: Evans-Tischenko reaction;
DOI:10.1021/ja011211m

Reference yield:

: 261968-12-1
1-(p-methoxybenzyloxy)-5-hydroxy-2,4,6-trimethyl-6-hepten-3-one

: 261968-14-3
6-[1-(p-methoxybenzyloxy)-2-propyl]-2-(phenylseleno)methyl-4-isopropenyl-[1,3]-dioxane

Guidance literature:: Multi-step reaction with 3 steps

1: 96 percent / SmI₂ / tetrahydrofuran / 1.5 h / -10 °C

2: 97 percent / K₂CO₃ / methanol; H₂O / 5 h / 20 °C

3: 94 percent / PPTS / toluene / 4 h / Heating

With samarium diiodide; pyridinium p-toluenesulfonate; potassium carbonate; In tetrahydrofuran; methanol; water; toluene; 1: Evans-Tischenko reaction;
DOI:10.1021/ja011211m