Methylene dibutyldithiocarbamate

Base Information

• Chemical Name: Methylene dibutyldithiocarbamate
• CAS No.: 10254-57-6
• Deprecated CAS: 107044-32-6,135409-60-8,147845-99-6,94434-53-4,135409-60-8,147845-99-6,94434-53-4
• Molecular Formula: C19H38 N2 S4
• Molecular Weight: 422.788
• Hs Code.: 2930909090
• European Community (EC) Number: 233-593-1
• UNII: 8074XM58IX
• DSSTox Substance ID: DTXSID5029718
• Nikkaji Number: J157.833B
• Wikidata: Q27269121
• Mol file: 10254-57-6.mol

Synonyms:10254-57-6;Methylene dibutyldithiocarbamate;Carbamodithioic acid, dibutyl-, methylene ester;4,4'-Methylene bis(dibutyldithiocarbamate);Bis(di-n-butylthiocarbamoylthio)methane;dibutylcarbamothioylsulfanylmethyl N,N-dibutylcarbamodithioate;UNII-8074XM58IX;Methylene bis(dibutylthiocarbamate);EINECS 233-593-1;Dibutyl-carbamodithioic acid, methylene ester;8074XM58IX;methylene bis[dibutyl(dithiocarbamate)];Carbamodithioic acid, N,N-dibutyl-, C,C'-methylene ester;4,4/'-Methylene bis(dibutyldithiocarbamate);EC 233-593-1;C19H38N2S4;SCHEMBL283658;DTXSID5029718;methylene bis(dibutyldithiocarbamate);methylene bis(dibutylcarbamodithioate);C19-H38-N2-S4;methylene esterdibutyl-carbamodithioic acid;LS-163132;4,4'-Methylene bis (dibutyldithiocarbamate);FT-0628878;V-7723;W-110263;Q27269121

Chemical Property of Methylene dibutyldithiocarbamate

Chemical Property:

• Vapor Pressure: 0Pa at 20℃
• Boiling Point: 486.7°Cat760mmHg
• PKA: 1.09±0.50(Predicted)
• Flash Point: 248.1°C
• PSA: 121.26000
• Density: 1.071g/cm³
• LogP: 6.78450
• Water Solubility.: 243μg/L at 20℃
• XLogP3: 7.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 16
• Exact Mass: 422.19178391
• Heavy Atom Count: 25
• Complexity: 302

Purity/Quality:

99.9% ^*data from raw suppliers

Bis(di-n-Butylthiocarbamoylthio)methane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCN(CCCC)C(=S)SCSC(=S)N(CCCC)CCCC

Technology Process of Methylene dibutyldithiocarbamate

There total 3 articles about Methylene dibutyldithiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.6%

carbon disulfide (75-15-0,12122-00-8) + dichloromethane (75-09-2) + dibutylamine (111-92-2) → methylene bis-(di-n-butylamino-dithioformate) (10254-57-6)

Guidance literature:

With sodium hydroxide; In water; at 70 ℃; for 0.0152778h; under 6000.6 Torr; Temperature; Pressure; Time;

Reference yield: 93.0%

carbon disulfide (75-15-0,12122-00-8) + dibutylamine (111-92-2) → methylene bis-(di-n-butylamino-dithioformate) (10254-57-6)

Guidance literature:

With sodium hydroxide; In dichloromethane; water; at 25 - 70 ℃; for 6h; Solvent; Temperature;

Reference yield: 80.0%

dichloromethane (75-09-2) + sodium dibutyl dithiocarbamate (136-30-1) → methylene bis-(di-n-butylamino-dithioformate) (10254-57-6)

Guidance literature:

With poly(ethylene glycol) 1,500 (PEG-1,500); In water; for 12h; Ambient temperature;

upstream raw materials:

dichloromethane

sodium dibutyl dithiocarbamate

carbon disulfide

dibutylamine

Downstream raw materials:

(Au(C₆F₅))2(CH₂(S₂CN((CH₂)3CH₃)2)2)

(Au(C₆F₅)3)2(CH₂(S₂CN((CH₂)3CH₃)2)2)

Refernces

• 1、 -. "Preparation method for dialkyl dithiocarbamate and anti-wear and rust-proof composite agent". Paragraph 0046; 0047; 0048; 0049; 0050; 0051; 0052; 0053. . Retrieved 2018/04/01.
• 2、 -. "PROCESS FOR PREPARING METHYLENE BIS-(DIALKYLAMINO-DITHIOFORMATE) IN ONE STEP". Paragraph 0052. . Retrieved 2015/01/06.