(Z)-1,2,3,3,3-Pentafluoropropene

Base Information

• Chemical Name: (Z)-1,2,3,3,3-Pentafluoropropene
• CAS No.: 2252-83-7
• Molecular Formula: C₃HF₅
• Molecular Weight: 132.033
• Hs Code.: 2903399090
• European Community (EC) Number: 226-875-0,823-491-0
• DSSTox Substance ID: DTXSID001027281
• Nikkaji Number: J1.100.113K,J210.571C
• Wikipedia: 1,2,3,3,3-Pentafluoropropene
• Wikidata: Q2403411
• Mol file: 2252-83-7.mol

Synonyms:1,2,3,3,3-pentafluoropropene

Chemical Property of (Z)-1,2,3,3,3-Pentafluoropropene

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 1.336g/cm³
• LogP: 2.32910
• XLogP3: 1.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 131.99984084
• Heavy Atom Count: 8
• Complexity: 98.7

Purity/Quality:

97% ^*data from raw suppliers

1,2,3,3,3-Pentafluoropropene 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F
• Safety Statements: 3/7-9-23

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=C(C(F)(F)F)F)F
• Isomeric SMILES: C(=C(/C(F)(F)F)\F)\F

Technology Process of (Z)-1,2,3,3,3-Pentafluoropropene

There total 14 articles about (Z)-1,2,3,3,3-Pentafluoropropene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.9%

1,1,1,2,3,3-hexafluoropropane (431-63-0) → 1,2,3,3,3-pentafluoroprop-1-ene (2252-83-7,5528-43-8,5595-10-8)

Guidance literature:

With potassium hydroxide; In water; at 155 - 170 ℃; for 6h; Product distribution / selectivity;

Reference yield: 29.0%

perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) → 1,2,3,3,3-pentafluoroprop-1-ene (2252-83-7,5528-43-8,5595-10-8) + trans-1,3,3,3-tetrafluoropropene (29118-24-9) + (Z)-1,3,3,3-tetrafluoropropene (29118-25-0)

Guidance literature:

With dimethylsulfide borane complex; In benzene-d6; at 100 ℃; for 96h; Time;

Reference yield:

1,1,2-trichloro-1,2,3,3,3-pentafluoropropane (812-30-6) → 1,2,3,3,3-pentafluoroprop-1-ene (2252-83-7,5528-43-8,5595-10-8) + 1,1,1-trifluoropropane (421-07-8) + 1,1,1,2,3-pentafluoropropane (431-31-2) + 1,1,1-trifluoropropylene (677-21-4) + 2,3,3,3-tetrafluoro-propene (754-12-1) + Z-1,2,3,3,3-pentafluoropropene (5528-43-8)

Guidance literature:

With hydrogen fluoride; hydrogen; at 300 ℃; for 0.00833333h; under 760.051 Torr; Product distribution / selectivity;

upstream raw materials:

1,1,1,2,3,3-hexafluoropropane

3-chloro-1,1,1,2,2,3-hexafluoropropane

ethyl-dimethyl-(2,2,3,3,3-pentafluoro-propyl)-ammonium; hydroxide

1,1,1,2,3-pentafluoropropane

Downstream raw materials:

2,3-dichloro-1,1,1,2,3-pentafluoropropane

Methyl 1,2,3,3,3-pentafluorpropylether

1,1,1,2,3-pentafluoropropane

1,1,1,2,3,3-hexafluoropropane

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