[Fe(II)(1,4,8,12-tetraazacyclopentadecane)(SC₆H₄-p-NO₂)]BF₄

Base Information

• Chemical Name: [Fe(II)(1,4,8,12-tetraazacyclopentadecane)(SC₆H₄-p-NO₂)]BF₄
• CAS No.: 1073190-07-4
• Molecular Formula: BF₄*C₁₇H₃₀FeN₅O₂S
• Molecular Weight: 511.175
• Mol file: 1073190-07-4.mol

Synonyms:[Fe(II)(1,4,8,12-tetraazacyclopentadecane)(SC₆H₄-p-NO₂)]BF₄

Chemical Property of [Fe(II)(1,4,8,12-tetraazacyclopentadecane)(SC₆H₄-p-NO₂)]BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Fe(II)(1,4,8,12-tetraazacyclopentadecane)(SC₆H₄-p-NO₂)]BF₄

There total 1 articles about [Fe(II)(1,4,8,12-tetraazacyclopentadecane)(SC₆H₄-p-NO₂)]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

1,4,8,12-Tetraazacyclopentadecan (15439-16-4) + iron(II) tetrafluoroborate hexahydrate + sodium 4-nitrobenzenethiolate (13113-79-6) → [Fe(II)(1,4,8,12-tetraazacyclopentadecane)(SC6H4-p-NO2)]BF4 (1073190-07-4)

Guidance literature:

In methanol; byproducts: NaBF4; (N2 or Ar, Schlenk) to a soln. of Fe(BF4)2 in methanol was added a soln.of tetraamine-compound in methanol dropwise, stirred for 30 min, a meth anolic soln. of Na-thiolate was added, the mixt. was stirred overnight; methanol was removed under vac., ppt. was dissolved in CH2Cl2, filtered,vapor diffusion of diethyl ether for 1 d; elem. anal.;

DOI:10.1021/ja8031828

Reference yield:

tert.-butylhydroperoxide (75-91-2) + [Fe(II)(1,4,8,12-tetraazacyclopentadecane)(SC6H4-p-NO2)]BF4 (1073190-07-4) → [Fe(II)([15]aneN4)(SC6H4-p-NO2)(OO-t-Bu)]BF4 (1073190-15-4)

Guidance literature:

In decane; dichloromethane; (N2 or Ar, Schlenk) to a soln. of complex in CH2Cl2 at -78°C was added 3 equiv of peroxide-compound in n-decane diluted with CH2Cl2; not sepd., detected by UV spectra;

DOI:10.1021/ja8031828

Reference yield:

[Fe(II)(1,4,8,12-tetraazacyclopentadecane)(SC6H4-p-NO2)]BF4 (1073190-07-4) + Cumene hydroperoxide (80-15-9) → [Fe(II)([15]aneN4)(SC6H4-p-NO2)(OO-cumenyl)]BF4 (1073190-21-2)

Guidance literature:

In dichloromethane; (N2 or Ar, Schlenk) to a soln. of complex in CH2Cl2 at -78°C was added 3 equiv of peroxide-compound in CH2Cl2, Ar or N2-bubbling; not sepd., detected by UV spectra;

DOI:10.1021/ja8031828

upstream raw materials:

1,4,8,12-Tetraazacyclopentadecan

sodium 4-nitrobenzenethiolate

Downstream raw materials:

[Fe(II)([15]aneN₄)(SC₆H₄-p-NO₂)(OO-t-Bu)]BF₄

[Fe(II)([15]aneN₄)(SC₆H₄-p-NO₂)(OO-cumenyl)]BF₄

[Fe(III)(1,4,8,12-tetraazacyclopentadecane)(SC₆H₄-p-NO₂)(t-butylperoxo)]BF₄