13113-79-6Relevant articles and documents
Solvent effects on reactions of hydroxide ion with phosphorus (V) esters. A quantitative treatment
Bunton, Clifford A.,Gillitt, Nicholas D.,Kumar, Anurag
, p. 145 - 151 (1996)
Second-order rate constants of reactions of HO- with phosphate, phosphinate and thiophosphinate esters, (PhO)2PO.OC6H4NO2-p, Ph2PO.OC6H4NO2-p, Ph2PO.SPh, Ph2PO.SC6H4NO2-p and Ph2PO.SEt, go through minima with decreasing water content of H2O-MeCN or H2O-t-BuOH. The rate decrease is due to stabilization of the non-ionic ester on addition of organic solvent to H2O. This inhibition is partially offset by stabilization of the anionic transition states and in the drier solvents partial desolvation of HO- increases rates.
Structurally homologous sialidases exhibit a commonality in reactivity: Glycoside hydrolase-catalyzed hydrolysis of Kdn-thioglycosides
Nejatie, Ali,Akintola, Oluwafemi,Steves, Elizabeth,Shamsi Kazem Abadi, Saeideh,Moore, Margo M.,Bennet, Andrew J.
, (2021)
Aspergillus fumigatus is one of the main causative agents of invasive aspergillosis, an often-lethal fungal disease that affects immunocompromised individuals. A. fumigatus produces a sialidase that cleaves the nine-carbon carbohydrate Kdn from glycoconju
IMIDATE COMPOUND AND USE THEREOF FOR PEST CONTROL
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Page/Page column 217-218, (2009/03/07)
There is provided a compound having an excellent controlling effect on arthropod pests represented by the formula (I-1): wherein Z represents an optionally substituted carbocyclic group or an optionally substituted heterocyclic group; G represents a -A1-R1