Technology Process of (m-(methylsulfonyl)phenyl)chlorodiazirine
There total 4 articles about (m-(methylsulfonyl)phenyl)chlorodiazirine which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 1.331 g / m-chloroperoxybenzoic acid / CH2Cl2 / 5.66 h / 0 - 20 °C
2: 1.) MeONa, 2.) NH4Cl / 1.) MeOH, 45 deg C, 23 h, 2.) MeOH, 45 deg C, 24 h
3: 33 percent / sodium hypochlorite
With
sodium hypochlorite; sodium methylate; ammonium chloride; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
DOI:10.1021/ja00070a003
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 1.) HCl, aq. NaNO2, 2.) Na2CO3 / 2.) toluene, from 0 deg C to RT, 120 min
2: 1.331 g / m-chloroperoxybenzoic acid / CH2Cl2 / 5.66 h / 0 - 20 °C
3: 1.) MeONa, 2.) NH4Cl / 1.) MeOH, 45 deg C, 23 h, 2.) MeOH, 45 deg C, 24 h
4: 33 percent / sodium hypochlorite
With
hydrogenchloride; sodium hypochlorite; sodium methylate; sodium carbonate; ammonium chloride; 3-chloro-benzenecarboperoxoic acid; sodium nitrite;
In
dichloromethane;
DOI:10.1021/ja00070a003
