[chloro(bis[(2-diphenylphosphino)ethyl]phenylphosphine)platinum(II)] chloride

Base Information

• Chemical Name: [chloro(bis[(2-diphenylphosphino)ethyl]phenylphosphine)platinum(II)] chloride
• CAS No.: 33847-49-3
• Molecular Formula: C₃₄H₃₃ClP₃Pt*Cl
• Molecular Weight: 800.543
• Mol file: 33847-49-3.mol

Synonyms:[chloro(bis[(2-diphenylphosphino)ethyl]phenylphosphine)platinum(II)] chloride

Chemical Property of [chloro(bis[(2-diphenylphosphino)ethyl]phenylphosphine)platinum(II)] chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [chloro(bis[(2-diphenylphosphino)ethyl]phenylphosphine)platinum(II)] chloride

There total 4 articles about [chloro(bis[(2-diphenylphosphino)ethyl]phenylphosphine)platinum(II)] chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3) + bis(2-diphenylphosphinoethyl)phenylphosphine (23582-02-7) → [chloro(bis[(2-diphenylphosphino)ethyl]phenylphosphine)platinum(II)] chloride (33847-49-3)

Guidance literature:

In benzene; soln. of ligand in benzene was added to refluxing soln. of Pt-complex inbenzene, stirred for 1 h, cooled to room temp.; filtered off, washed with benzene, dried under reduced pressure; elem. anal.;

DOI:10.1016/S0020-1693(00)00329-7

Reference yield: 91.0%

bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3) + bis(2-diphenylphosphinoethyl)phenylphosphine (23582-02-7) → [Pt(bis(2-diphenylphosphinoethyl)phenylphosphine)Cl]Cl (33847-49-3)

Guidance literature:

In benzene; a soln. of triphos in benzene was added to the refluxing soln. of complex, stirred for 1 h then cooled to room temp.; ppt. was filtered off, washed with benzene and dried under vac.; elem. anal.;

DOI:10.1016/S0020-1693(00)00042-6

Reference yield: 81.4%

dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + bis(2-diphenylphosphinoethyl)phenylphosphine (23582-02-7) → [chloro(bis[(2-diphenylphosphino)ethyl]phenylphosphine)platinum(II)] chloride (33847-49-3)

Guidance literature:

In dichloromethane; (N2); standing (30 min); vac. evapn., washing (Et2O), recrystn. (CH2Cl2, C7H16), vac. drying;

DOI:10.1021/ja952680p

upstream raw materials:

bis(benzonitrile)dichloroplatinum(II)

bis(2-diphenylphosphinoethyl)phenylphosphine

dichloro(1,5-cyclooctadiene)platinum(ll)

potassium tetrachloroplatinate(II)

Downstream raw materials:

[Pt(P(C₆H₅)2C₂H₄P(C₆H₅)C₂H₄P(C₆H₅)2)CN]⁽¹⁺⁾*CN^(1-)=[Pt(P(C₆H₅)2C₂H₄P(C₆H₅)C₂H₄P(C₆H₅)2)CN]CN

PtNO₃(C₆H₅)2PCH₂CH₂PC₆H₅CH₂CH₂P(C₆H₅)2⁽¹⁺⁾*NO₃^(1-)=PtNO₃(C₆H₅)2PCH₂CH₂PC₆H₅CH₂CH₂P(C₆H₅)2NO₃

[chloro(bis(2-diphenylphosphinoethyl)phenylphosphine)platinum(II)][SnPh₂Cl₃]

Pt(C₃₄H₃₃P₃)(C₁₀H₁₅N₃O₆S)