tetraphenylbismuth 2,4-dimethylbenzenesulfonate

Base Information

• Chemical Name: tetraphenylbismuth 2,4-dimethylbenzenesulfonate
• CAS No.: 265662-34-8
• Molecular Formula: C₃₂H₂₉BiO₃S
• Molecular Weight: 702.627
• Mol file: 265662-34-8.mol

Synonyms:tetraphenylbismuth 2,4-dimethylbenzenesulfonate

Chemical Property of tetraphenylbismuth 2,4-dimethylbenzenesulfonate

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of tetraphenylbismuth 2,4-dimethylbenzenesulfonate

There total 5 articles about tetraphenylbismuth 2,4-dimethylbenzenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

2,4-dimethylbenzenesulfonic acid (88-61-9) + pentaphenylbismuth (3049-07-8) → tetraphenylbismuth 2,4-dimethylbenzenesulfonate (265662-34-8)

Guidance literature:

In acetone; soln. Bi-compd. addn. to soln. of ligand; solvent removing, recrystallization (benzene);

Reference yield: 81.0%

diphenylbismuth 2,4-dimethylbenzenesulfonate (329055-56-3) + pentaphenylbismuth (3049-07-8) → tetraphenylbismuth 2,4-dimethylbenzenesulfonate (265662-34-8) + triphenylbismuthane (603-33-8)

Guidance literature:

In diethyl ether; mixed, stirred for 12 h at 20°C, evapd.; recrystd. (water), elem. anal.;

DOI:10.1023/A:1023619616897

Reference yield: 81.0%

diphenylbismuth 2,4-dimethylbenzenesulfonate (329055-56-3) + bromine (7726-95-6) → tetraphenylbismuth 2,4-dimethylbenzenesulfonate (265662-34-8)

Guidance literature:

In diethyl ether; to soln. of Bi sulfonate in ether added Br2, kept for 48 h at 20°C; concd., extracted (toluene), filtered, removed of solvent;

DOI:10.1023/A:1023475615290

upstream raw materials:

diphenylbismuth 4-methylbenzenesulfonate

diphenylbismuth 2,4-dimethylbenzenesulfonate

bromine

pentaphenylbismuth