1-Methoxymethoxy-4-methoxy-2-(3-methyl-2-butenyl)benzene

Base Information

Chemical Name:1-Methoxymethoxy-4-methoxy-2-(3-methyl-2-butenyl)benzene
CAS No.:307492-77-9
Molecular Formula:C₁₄H₂₀O₃
Molecular Weight:236.311
Hs Code.:
DSSTox Substance ID:DTXSID701181408
Nikkaji Number:J1.412.270B

Synonyms:DTXSID701181408;1-Methoxymethoxy-4-methoxy-2-(3-methyl-2-butenyl)benzene;4-Methoxy-1-(methoxymethoxy)-2-(3-methyl-2-buten-1-yl)benzene;307492-77-9

Suppliers and Price of 1-Methoxymethoxy-4-methoxy-2-(3-methyl-2-butenyl)benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-Methoxymethoxy-4-methoxy-2-(3-methyl-2-butenyl)benzene

Chemical Property:

XLogP3:3.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:6
Exact Mass:236.14124450
Heavy Atom Count:17
Complexity:234

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(=CCC1=C(C=CC(=C1)OC)OCOC)C

Technology Process of 1-Methoxymethoxy-4-methoxy-2-(3-methyl-2-butenyl)benzene

There total 2 articles about 1-Methoxymethoxy-4-methoxy-2-(3-methyl-2-butenyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 25458-46-2
4-methoxyphenyl methoxymethyl ether

: 870-63-3
prenyl bromide

: 307492-77-9
4-methoxy-1-(methoxymethoxy)-2-(3-methylbut-2-en-1-yl)benzene

Guidance literature:: 4-methoxyphenyl methoxymethyl ether; With n-butyllithium; In tetrahydrofuran; diethyl ether; hexane; at 25 ℃; for 6h;

prenyl bromide; With copper(l) iodide; In tetrahydrofuran; diethyl ether; hexane; at -78 ℃;
DOI:10.1002/1099-0690(200009)2000:18<3223::AID-EJOC3223>3.0.CO;2-L

Reference yield:

: 150-76-5
4-methoxy-phenol

: 307492-77-9
4-methoxy-1-(methoxymethoxy)-2-(3-methylbut-2-en-1-yl)benzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: 97 percent / iPr₂NEt / CH₂Cl₂ / 12 h / 40 °C

2.1: nBuLi / tetrahydrofuran; hexane; diethyl ether / 6 h / 25 °C

2.2: 85 percent / CuI / tetrahydrofuran; hexane; diethyl ether / -78 °C

With n-butyllithium; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; 1.1: Alkylation / 2.1: Metallation;
DOI:10.1002/1099-0690(200009)2000:18<3223::AID-EJOC3223>3.0.CO;2-L

Reference yield: 80.0%

: 307492-77-9
4-methoxy-1-(methoxymethoxy)-2-(3-methylbut-2-en-1-yl)benzene

: 434928-87-7
(E)-2-(4-hydroxy-3-methylbut-3-en-1-yl)-4-methoxy-1-methoxymethoxybenzene

Guidance literature:: 4-methoxy-1-(methoxymethoxy)-2-(3-methylbut-2-en-1-yl)benzene; With selenium(IV) oxide; In ethanol; for 0.5h; Heating;

With sodium tetrahydroborate; In ethanol; at 0 ℃; for 1h;
DOI:10.1002/1099-0690(200009)2000:18<3223::AID-EJOC3223>3.0.CO;2-L