triphenylarsineacetylbenzoylmethylene

Base Information

• Chemical Name: triphenylarsineacetylbenzoylmethylene
• CAS No.: 86001-88-9
• Molecular Formula: C₂₈H₂₃AsO₂
• Molecular Weight: 466.411
• Mol file: 86001-88-9.mol

Synonyms:triphenylarsineacetylbenzoylmethylene

Chemical Property of triphenylarsineacetylbenzoylmethylene

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of triphenylarsineacetylbenzoylmethylene

There total 14 articles about triphenylarsineacetylbenzoylmethylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

triphenyl-arsane (603-32-7) + 2-phenyliodonio-1-phenylbutane-1,3-dione (128753-04-8) → triphenylarsineacetylbenzoylmethylene (86001-88-9)

Guidance literature:

Cu(II) complex of benzoylacetone; In ethanol; for 2h; Heating;

DOI:10.1016/0040-4020(82)80118-X

Reference yield: 55.0%

(2-oxo-2-phenylethyl)triphenylarsonium bromide (42350-78-7) + acetyl chloride (75-36-5) → triphenylarsineacetylbenzoylmethylene (86001-88-9)

Guidance literature:

With triethylamine; In chloroform; at 0 - 24 ℃;

DOI:10.1080/00397910008087412

Reference yield: 45.0%

benzoyl chloride (98-88-4) + [(methoxycarbonyl)methyl]triphenylarsonium bromide (1529-78-8) → triphenylarsineacetylbenzoylmethylene (86001-88-9)

Guidance literature:

With triethylamine; In chloroform; at 0 - 24 ℃;

DOI:10.1080/00397910008087412

upstream raw materials:

triphenyl-arsane

2-phenyliodonio-1-phenylbutane-1,3-dione

sodium benzoate

sodium acetate

Downstream raw materials:

(1-Benzoyl-2-oxo-propyl)-triphenyl-arsonium; bromide

(1-Benzoyl-2-oxo-propyl)-triphenyl-arsonium; chloride

Refernces

• 1、 Nesmeyanov, N. A.,Kharitonov, V. G.,Berman, S. T.,Petrovskii, P. V.,Reutov, O. A.. "ACYLATION OF ARSENIC β-KETOYLIDES BY CARBOXYLIC ACID HALIDES". . p. 165 - 170. Retrieved 2007/10/02.