128753-04-8

Upstream product

• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 93-91-4 1-phenylbutan-1,3-dione 

Downstream Products

• 86001-88-9 triphenylarsineacetylbenzoylmethylene 
• 13128-32-0 1-(1-hydroxy-4-phenylnaphthalen-2-yl)ethan-1-one 
• 18703-72-5 2-methyl-3-benzoyl<2.3>benzofuran 
• 4265-21-8 3-acetyl-2-phenylbenzofuran 
• 1206821-35-3 C₂₂H₂₉NO₃ 
• 1206821-38-6 C₂₁H₂₅NO₃ 
• 1206821-37-5 C₁₉H₂₃NO₃ 
• 1206821-36-4 C₁₈H₁₉NO₃ 
• 109801-25-4 2-fluoro-1-phenyl-1,3-butanedione 
• 1464963-65-2 1-(2-benzoyl-1-tosylindolin-2-yl)ethanone 
• 1464963-67-4 1-(2-benzoyl-1-(phenylsulfonyl)indolin-2-yl)ethanone 
• 1464963-69-6 1-(2-benzoyl-1-((4-fluorophenyl)sulfonyl)indolin-2-yl)ethanone 
• 1464964-03-1 1-(2-benzoyl-5,6-dimethoxy-1-tosylindolin-2-yl)ethanone 

Relevant academic research and scientific papers

Reaction of iodonium ylides of 1,3-dicarbonyl compounds with HF reagents

Reaction of dibenzoylmethane with (diacetoxyiodo)benzene in the presence of KOH in MeCN quantitatively gave the corresponding iodonium ylide, which was treated with a HF reagent to afford the corresponding 2-fluorinated dibenzoylmethane in 14-50% yields.

Transition-metal-free approach to synthesis of indolines from N-(ortho-chloromethyl)aryl amides and iodonium ylides

A transition-metal-free method for the synthesis of indolines has been developed. In the presence of K2CO3, the cyclization reaction of N-(ortho-chloromethyl)aryl amides and iodonium ylides proceeded smoothly at room temperature in moderate to good yields.