phenylchlorodiazomethane

Base Information

• Chemical Name: phenylchlorodiazomethane
• CAS No.: 19016-92-3
• Molecular Formula: C₇H₅ClN₂
• Molecular Weight: 152.583
• Mol file: 19016-92-3.mol

Synonyms:phenylchlorodiazomethane

Chemical Property of phenylchlorodiazomethane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenylchlorodiazomethane

There total 4 articles about phenylchlorodiazomethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-chloro-3-phenyl-3H-diazirine (4460-46-2) → carbon dioxide (124-38-9,18923-20-1) + carbon monoxide (201230-82-2) + phenylchlorodiazomethane (19016-92-3) + benzoyl chloride (98-88-4) + phenyl chloroformate (1885-14-9) + 1-chlorocyclohepta-1,2,4,6-tetraene (107135-21-7)

Guidance literature:

With oxygen; In solid matrix; at -263.2 ℃; Product distribution; Mechanism; Irradiation; different O₂ concentrations and wavelengths of irradiation;

DOI:10.1016/0584-8539(87)80146-0

Reference yield:

benzamidine monohydrochloride (1670-14-0) → phenylchlorodiazomethane (19016-92-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 51 percent / sodium chloride, 5.25 percent sodium hypochlorite / hexane; dimethylsulfoxide / 0.5 h / 0 °C

2: Irradiation; irradiation ( λ=372-392 nm); argon matrix-isolated 17c; var.: (1.) flash vacuum thermolysis, 400 deg C, 2.) cocondensation with argon)

With sodium hypochlorite; sodium chloride; In hexane; dimethyl sulfoxide;

DOI:10.1021/ja00242a034

Reference yield:

3-chloro-3-phenyl-3H-diazirine (4460-46-2) → chlorophenylcarbene (19807-41-1) + phenylchlorodiazomethane (19016-92-3)

Guidance literature:

Irradiation; irradiation ( λ=372-392 nm); argon matrix-isolated 17c; var.: (1.) flash vacuum thermolysis, 400 deg C, 2.) cocondensation with argon);

DOI:10.1021/ja00242a034

upstream raw materials:

3-chloro-3-phenyl-3H-diazirine

benzamidine monohydrochloride

Downstream raw materials:

9-Chlor-exo-9-phenylbicyclo<6.1.0>nona-2,4,6-trien

exo-9-Chlor-endo-9-phenylbicyclo<6.1.0>nona-2,4,6-trien

(CH₃CH₂CH₂CH₂)3SnCHClC₆H₅

C₃₅H₂₆O