(3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-yl acrylate

Base Information

Chemical Name:(3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-yl acrylate
CAS No.:918637-45-3
Molecular Formula:C₂₃H₃₃NO₃S
Molecular Weight:403.586
Hs Code.:

Synonyms:(3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-yl acrylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-yl acrylate

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Technology Process of (3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-yl acrylate

There total 2 articles about (3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-yl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 918637-44-2
(3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-ol

: 79-10-7
acrylic acid

: 918637-45-3
(3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-yl acrylate

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 0 - 25 ℃; for 12h; Inert atmosphere;
DOI:10.1002/chem.201103060

Reference yield:

: 918637-19-1
C₂₃H₄₁NO₂SSi

: 918637-45-3
(3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-yl acrylate

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / -78 - 0 °C / Inert atmosphere

1.2: 3 h / -45 - 20 °C / Inert atmosphere

2.1: pyridine hydrogenfluoride / tetrahydrofuran; water / 3 h / 20 °C / Inert atmosphere

3.1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 12 h / 0 - 25 °C / Inert atmosphere

With dmap; n-butyllithium; pyridine hydrogenfluoride; dicyclohexyl-carbodiimide; In tetrahydrofuran; hexane; dichloromethane; water;
DOI:10.1002/chem.201103060

Reference yield: 87.0%

: 918637-45-3
(3S,4R,E)-4-isopropyl-2-methyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]nona-5,8-dien-3-yl acrylate

: 918637-47-5
(3Z,6E,8R,9S)-8,9-diisopropyl-6-[(S)-N-methyl-S-phenylsulfonimidoyl]-8,9-dihydro-oxonin-2(5H)-one

Guidance literature:: With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In toluene; for 16h; Inert atmosphere; Reflux;
DOI:10.1002/chem.201103060