9-Fluorenylmethyl N-hydroxycarbamate

Base Information

Chemical Name:9-Fluorenylmethyl N-hydroxycarbamate
CAS No.:190656-01-0
Molecular Formula:C15H13 N O3
Molecular Weight:255.273
Hs Code.:2924299090
European Community (EC) Number:626-969-5
DSSTox Substance ID:DTXSID70407926
Nikkaji Number:J836.206H
Wikidata:Q72478837
Mol file:190656-01-0.mol

Synonyms:190656-01-0;9-Fluorenylmethyl N-hydroxycarbamate;N-Fmoc-hydroxylamine;(9H-fluoren-9-yl)methyl hydroxycarbamate;9H-fluoren-9-ylmethyl N-hydroxycarbamate;MFCD01862911;Carbamic acid, N-hydroxy-, 9H-fluoren-9-ylmethyl ester;Fmoc-NH-OH;Fmoc-Aminoalkohol;Fmoc Hydroxylamine;SCHEMBL1800381;DTXSID70407926;HHNJBGORPSTJDX-UHFFFAOYSA-N;AKOS030212638;(9H-fluoren-9-yl)methylhydroxycarbamate;AS-10726;SY251534;CS-0160446;N-(9-Fluorenylmethyloxycarbonyl)hydroxylamine;C93439;9-Fluorenylmethyl N-hydroxycarbamate, >=99.0%;EN300-7074374;N-(9H-Fluoren-9-ylmethoxycarbonyl)hydroxylamine;A934484;(9H-FLUOREN-9-YL)METHYL N-HYDROXYCARBAMATE;J-012307

Suppliers and Price of 9-Fluorenylmethyl N-hydroxycarbamate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
9-Fluorenylmethyl N-hydroxycarbamate ≥99.0%
5g
$ 162.00

Iris Biotech GmbH
Fmoc-NH-OH
5 g
$ 249.75

Crysdot
(9H-Fluoren-9-yl)methylhydroxycarbamate 97%
100g
$ 475.00

Chem-Impex
N-Fmoc-hydroxylamine,99%(HPLC) 99%(HPLC)
5G
$ 128.80

Chem-Impex
N-Fmoc-hydroxylamine,≥99%(HPLC) ≥99%(HPLC)
1G
$ 34.94

Chem-Impex
N-Fmoc-hydroxylamine,99%(HPLC) 99%(HPLC)
25G
$ 616.00

American Custom Chemicals Corporation
9-FLUORENYLMETHYL N-HYDROXYCARBAMATE 95.00%
5G
$ 938.06

Ambeed
(9H-Fluoren-9-yl)methylhydroxycarbamate 97%
25g
$ 163.00

Ambeed
(9H-Fluoren-9-yl)methylhydroxycarbamate 97%
5g
$ 52.00

Ambeed
(9H-Fluoren-9-yl)methylhydroxycarbamate 97%
1g
$ 16.00

Total 17 raw suppliers

Chemical Property of 9-Fluorenylmethyl N-hydroxycarbamate

Chemical Property:

Vapor Pressure:6E-11mmHg at 25°C
Melting Point:164.5 °C(lit.)
Refractive Index:1.634
Boiling Point:503.2°C at 760 mmHg
Flash Point:258.2°C
PSA：58.56000
Density:1.304g/cm³
LogP:3.30520
Storage Temp.:2-8°C
XLogP3:2.6
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:255.08954328
Heavy Atom Count:19
Complexity:311

Purity/Quality:

98%,99%, ^*data from raw suppliers

9-Fluorenylmethyl N-hydroxycarbamate ≥99.0% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C2C(=C1)C(C3=CC=CC=C32)COC(=O)NO
Uses 9-Fluorenylmethyl N-hydroxycarbamate (Fmoc-NHOH) can be used as a reactant to prepare: N-Fmoc-aminooxy-2-chlorotrityl polystyrene, a solid-phase resin used to produce hydroxamic acids and peptidyl hydroxamic acids. 9-Fluorenylmethyl nosyloxycarbamate (Fmoc-NHONs) by reacting with nosyl chloride.

Technology Process of 9-Fluorenylmethyl N-hydroxycarbamate

There total 5 articles about 9-Fluorenylmethyl N-hydroxycarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: C₃₄H₂₇NO₃

: 190656-01-0
N-(9-fluorenylmethoxycarbonyloxy)hydroxylamine

Guidance literature:: With boron trifluoride diethyl etherate; In methanol; dichloromethane; at 20 ℃; for 0.75h;
DOI:10.1021/jo701411d

Reference yield: 90.0%

: 28920-43-6
(fluorenylmethoxy)carbonyl chloride

: 190656-01-0
N-(9-fluorenylmethoxycarbonyloxy)hydroxylamine

Guidance literature:: With hydroxylamine hydrochloride; sodium hydrogencarbonate; In water; ethyl acetate;
DOI:10.1016/S0040-4039(97)00594-7

Reference yield: 80.0%

: 82911-69-1
N-(9H-fluoren-2-ylmethoxycarbonyloxy)succinimide

: 190656-01-0
N-(9-fluorenylmethoxycarbonyloxy)hydroxylamine

Guidance literature:: With hydroxylamine hydrochloride; sodium hydrogencarbonate; In water; ethyl acetate; at 5 - 20 ℃; for 4h;
DOI:10.1016/j.bmcl.2012.10.107