pentafluorophenylmercaptogold

Base Information

• Chemical Name: pentafluorophenylmercaptogold
• CAS No.: 21459-32-5
• Molecular Formula: Au*C₆F₅S
• Molecular Weight: 396.091
• Mol file: 21459-32-5.mol

Synonyms:pentafluorophenylmercaptogold

Chemical Property of pentafluorophenylmercaptogold

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of pentafluorophenylmercaptogold

There total 7 articles about pentafluorophenylmercaptogold which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

carbonylgold(I) chloride (50960-82-2) + pentafluorophenylthiol (771-62-0) → pentafluorophenylmercaptogold (21459-32-5)

Guidance literature:

In toluene; byproducts: HCl, CO; N2-atmosphere; addn. of equimolar amt. of thiol to Au-complex (solid CO2-temp.), warming to 10°C (pptn.); collection (filtration), drying (vac.); elem. anal.;

DOI:10.1039/DT9950003917

Reference yield:

pentafluorophenylthiol (771-62-0) + gold(1+) (20681-14-5) → pentafluorophenylmercaptogold (21459-32-5)

Guidance literature:

In water; byproducts: H(1+); starting material is HAuCl4*3H2O; elimination of (C6F5S)2 with ether or methanol;

Reference yield:

pentafluorophenyl lithium (1076-44-4) → pentafluorophenylmercaptogold (21459-32-5)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran

2: water

In tetrahydrofuran; water;

upstream raw materials:

pentafluorophenylthiol

gold⁽¹⁺⁾

carbonylgold(I) chloride

Hexafluorobenzene

Downstream raw materials:

gold

Refernces