hydroxy(phenyl)-λ³-iodanyl diphenylphosphinate

Base Information

• Chemical Name: hydroxy(phenyl)-λ³-iodanyl diphenylphosphinate
• CAS No.: 189581-08-6
• Molecular Formula: C₁₈H₁₆IO₃P
• Molecular Weight: 438.202
• Mol file: 189581-08-6.mol

Synonyms:hydroxy(phenyl)-λ³-iodanyl diphenylphosphinate

Chemical Property of hydroxy(phenyl)-λ³-iodanyl diphenylphosphinate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of hydroxy(phenyl)-λ³-iodanyl diphenylphosphinate

There total 3 articles about hydroxy(phenyl)-λ³-iodanyl diphenylphosphinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

iodosylbenzene (536-80-1) + diphenyl-phosphinic acid (1707-03-5) → hydroxy(phenyl)-λ3-iodanyl diphenylphosphinate (189581-08-6)

Guidance literature:

In acetonitrile; for 2h; Ambient temperature;

DOI:10.1016/S0040-4039(97)00388-2

Reference yield: 78.0%

[bis(acetoxy)iodo]benzene (3240-34-4) + diphenyl-phosphinic acid (1707-03-5) → hydroxy(phenyl)-λ3-iodanyl diphenylphosphinate (189581-08-6)

Guidance literature:

[bis(acetoxy)iodo]benzene; diphenyl-phosphinic acid; In acetonitrile; at 20 ℃; for 1h;

With water; In acetonitrile; at 20 ℃; for 4h;

DOI:10.1002/anie.201304359

Reference yield:

iodobenzene (591-50-4) → hydroxy(phenyl)-λ3-iodanyl diphenylphosphinate (189581-08-6)

Guidance literature:

Multi-step reaction with 2 steps

1: lithium perchlorate / 2,2,2-trifluoroethanol / 7.5 h / 20 °C / Electrochemical reaction

2: acetonitrile / 0.5 h / 20 °C

With lithium perchlorate; In 2,2,2-trifluoroethanol; acetonitrile;

DOI:10.1002/cjoc.202000501

upstream raw materials:

iodosylbenzene

diphenyl-phosphinic acid

[bis(acetoxy)iodo]benzene

iodobenzene

Refernces

• 1、 Zu, Bing,Ke, Jie,Guo, Yonghong,He, Chuan. "Synthesis of Diverse Aryliodine(III) Reagents by Anodic Oxidation?". supporting information. p. 627 - 632. Retrieved 2021/02/12.