1-bromo-4-(1,1-dibromoprop-1-en-2-yl)benzene

Base Information

• Chemical Name: 1-bromo-4-(1,1-dibromoprop-1-en-2-yl)benzene
• CAS No.: 1174062-77-1
• Molecular Formula: C₉H₇Br₃
• Molecular Weight: 354.867
• Mol file: 1174062-77-1.mol

Synonyms:1-bromo-4-(1,1-dibromoprop-1-en-2-yl)benzene

Chemical Property of 1-bromo-4-(1,1-dibromoprop-1-en-2-yl)benzene

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 1-bromo-4-(1,1-dibromoprop-1-en-2-yl)benzene

There total 1 articles about 1-bromo-4-(1,1-dibromoprop-1-en-2-yl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

carbon tetrabromide (558-13-4) + para-bromoacetophenone (99-90-1) → 1-bromo-4-(1,1-dibromoprop-1-en-2-yl)benzene (1174062-77-1)

Guidance literature:

carbon tetrabromide; With triphenylphosphine; In toluene; at 110 ℃; for 0.25h; Inert atmosphere;

para-bromoacetophenone; In toluene; at 110 ℃; Inert atmosphere;

DOI:10.1002/ejoc.201901119

Reference yield: 55.0%

1-bromo-4-(1,1-dibromoprop-1-en-2-yl)benzene (1174062-77-1) + aniline (62-53-3) → 2-(4-bromophenyl)-N-phenylpropanamide (1174062-80-6)

Guidance literature:

With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; In 1,4-dioxane; water; for 24h; Inert atmosphere; Reflux;

DOI:10.1039/b904991f

Reference yield:

1-bromo-4-(1,1-dibromoprop-1-en-2-yl)benzene (1174062-77-1) → 1-bromo-4-(1-bromoprop-1-en-2-yl)benzene + (Z)-1-bromo-4-(1-bromoprop-1-en-2-yl)benzene

Guidance literature:

With triethylamine; phosphonic acid diethyl ester; at 0 - 65 ℃; for 48h; Overall yield = 53 percent; stereoselective reaction; Inert atmosphere;

DOI:10.1002/ejoc.201901119

upstream raw materials:

carbon tetrabromide

para-bromoacetophenone

Downstream raw materials:

2-(4-bromophenyl)-N-phenylpropanamide