N-(4,4-dimethoxy-2-methyl-cyclohexa-2,5-dienylidene)-benzamide

Base Information

• Chemical Name: N-(4,4-dimethoxy-2-methyl-cyclohexa-2,5-dienylidene)-benzamide
• CAS No.: 375385-70-9
• Molecular Formula: C₁₆H₁₇NO₃
• Molecular Weight: 271.316
• Mol file: 375385-70-9.mol

Synonyms:N-(4,4-dimethoxy-2-methyl-cyclohexa-2,5-dienylidene)-benzamide

Chemical Property of N-(4,4-dimethoxy-2-methyl-cyclohexa-2,5-dienylidene)-benzamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(4,4-dimethoxy-2-methyl-cyclohexa-2,5-dienylidene)-benzamide

There total 1 articles about N-(4,4-dimethoxy-2-methyl-cyclohexa-2,5-dienylidene)-benzamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

methanol (67-56-1) + N-(4-methoxy-2-methylphenyl)benzamide (61495-08-7) → N-(4,4-dimethoxy-2-methyl-cyclohexa-2,5-dienylidene)-benzamide (375385-70-9)

Guidance literature:

With lithium perchlorate; sodium hydrogencarbonate; Electrochemical reaction;

DOI:10.1139/v03-188

Reference yield: 92.0%

cyclohexa-1,3-diene (1165952-91-9) + N-(4,4-dimethoxy-2-methyl-cyclohexa-2,5-dienylidene)-benzamide (375385-70-9) → N-((1S,8R)-6-Methoxy-tricyclo[6.2.2.02,7]dodeca-2,4,6,9-tetraen-3-yl)-benzamide

Guidance literature:

cyclohexa-1,3-diene; N-(4,4-dimethoxy-2-methyl-cyclohexa-2,5-dienylidene)-benzamide; In dichloromethane; at 50 ℃; for 12h; under 9750780 Torr;

With hydrogenchloride; In tetrahydrofuran; for 0.0833333h;

DOI:10.1139/v03-188

Reference yield: 70.0%

(2E)-penta-2,4-dienyl pivalate + N-(4,4-dimethoxy-2-methyl-cyclohexa-2,5-dienylidene)-benzamide (375385-70-9) → [8-(benzoylamino)-5-methoxy-7-methyl-1,4-dihydronaphthalen-1-yl]methyl pivalate (375385-76-5)

Guidance literature:

(2E)-penta-2,4-dienyl pivalate; N-(4,4-dimethoxy-2-methyl-cyclohexa-2,5-dienylidene)-benzamide; In dichloromethane; at 50 ℃; for 12h; under 9750780 Torr;

With hydrogenchloride; In tetrahydrofuran; for 0.0833333h;

DOI:10.1139/v03-188

upstream raw materials:

methanol

N-(4-methoxy-2-methylphenyl)benzamide

Downstream raw materials:

[8-(benzoylamino)-5-methoxy-7-methyl-1,4-dihydronaphthalen-1-yl]methyl pivalate