Technology Process of ethyl 2-(4-octylphenoxy)acetate
There total 1 articles about ethyl 2-(4-octylphenoxy)acetate which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
potassium carbonate;
In
acetone;
for 5h;
Reflux;
- Guidance literature:
-
With
diisobutylaluminium hydride;
In
diethyl ether; hexane;
at 0 - 20 ℃;
for 2h;
Inert atmosphere;
DOI:10.1021/jm500192s
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: diisobutylaluminium hydride / diethyl ether; hexane / 2 h / 0 - 20 °C / Inert atmosphere
2.1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium hypochlorite; sodium bromide; sodium hydrogencarbonate / water; ethyl acetate; toluene / 1 h / 0 °C
3.1: n-butyllithium / diethyl ether; hexane / 0.17 h / -78 °C / Inert atmosphere
3.2: 2.5 h / -78 - 20 °C / Inert atmosphere
4.1: Dess-Martin periodane / dichloromethane / 1 h / 20 °C
With
sodium hypochlorite; n-butyllithium; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; sodium bromide;
In
diethyl ether; hexane; dichloromethane; water; ethyl acetate; toluene;
4.1: |Dess-Martin Oxidation;
DOI:10.1021/jm500192s
