1-ethyl-1',2'-cyclobutylferrocene

Base Information

• Chemical Name: 1-ethyl-1',2'-cyclobutylferrocene
• CAS No.: 842124-92-9
• Molecular Formula: C₁₄H₁₆Fe
• Molecular Weight: 240.128
• Mol file: 842124-92-9.mol

Synonyms:1-ethyl-1',2'-cyclobutylferrocene

Chemical Property of 1-ethyl-1',2'-cyclobutylferrocene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of 1-ethyl-1',2'-cyclobutylferrocene

There total 1 articles about 1-ethyl-1',2'-cyclobutylferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(C5H4C2H5)Fe(C5H4CH2CH2N(C2H5)2) (842125-02-4) + 1-[2-diethylamino]ethyl-1'-ethenylferrocene (842124-95-2) + (C5H3CH2CH2)Fe(C5H4CH2CH2N(C2H5)2) (842125-01-3) + hydrogen (1333-74-0) → 1,1'-diethylferrocene (1273-97-8) + 1-ethyl-1',2'-cyclobutylferrocene (842124-92-9)

Guidance literature:

With methyl iodide; t-BuOH; Pd/C; In tetrahydrofuran; under N2 atm. MeI was added to mixt. ferrocenes in THF, refluxed for 16 h, volatiles were removed in vacuo, t-BuOH and t-BuOK were added, refluxed for 15 h, cooled, CH2Cl2+H2O were added, org. phase was evapd., dissolved in EtOH, H2-Pd/C, 7 h; react. mixt. was filtered through Celite, filtrate was evapd. in vacuo, reversed-phase HPLC;

DOI:10.1021/om049222m

upstream raw materials:

(C₅H₄C₂H₅)Fe(C₅H₄CH₂CH₂N(C₂H₅)2)

1-[2-diethylamino]ethyl-1'-ethenylferrocene

(C₅H₃CH₂CH₂)Fe(C₅H₄CH₂CH₂N(C₂H₅)2)

hydrogen