(tetrakis(2,4,6-trimethylphenyl)porphyrinato)zinc(II)

Base Information

• Chemical Name: (tetrakis(2,4,6-trimethylphenyl)porphyrinato)zinc(II)
• CAS No.: 104025-54-9
• Molecular Formula: C₅₆H₅₂N₄Zn
• Molecular Weight: 846.446
• Mol file: 104025-54-9.mol

Synonyms:(tetrakis(2,4,6-trimethylphenyl)porphyrinato)zinc(II)

Chemical Property of (tetrakis(2,4,6-trimethylphenyl)porphyrinato)zinc(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (tetrakis(2,4,6-trimethylphenyl)porphyrinato)zinc(II)

There total 7 articles about (tetrakis(2,4,6-trimethylphenyl)porphyrinato)zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

5,10,15,20-tetramesitylporphyrin + zinc diacetate (557-34-6) → (tetrakis(2,4,6-trimethylphenyl)porphyrinato)zinc(II) (104025-54-9)

Guidance literature:

With 2,4,6-trimethyl-pyridine; In N,N-dimethyl-formamide; heating suspension of porphyrin (with collidine) at 150-160°C; addn.of zinc salt; refluxing for 1h; addn. of new fractions of zinc salt and collidine; heating for an extra 1h; cooling; pouring in dichloromethane; filtration; washing with water and small quantity of cold acetone; drying under vac.;

Reference yield: 96.0%

zinc(II) acetylacetonate (14024-63-6) + 5,10,15,20-tetramesitylporphyrin → (tetrakis(2,4,6-trimethylphenyl)porphyrinato)zinc(II) (104025-54-9)

Guidance literature:

In further solvent(s); heating the corresponding porphyrin in 1,2,4-trichlorobenzene at reflux wit Zn(acac)2, 30-35 min; evapn.; chromy. (alumina, CHCl3); evapn. of red main fraction; recrystn. from chloroform; elem. anal.;

Reference yield: 92.0%

5,10,15,20-tetramesitylporphyrin + zinc(II) acetate dihydrate (5970-45-6) → (tetrakis(2,4,6-trimethylphenyl)porphyrinato)zinc(II) (104025-54-9)

Guidance literature:

In methanol; chloroform; MeOH soln. of Zn(OAc)2*2H2O was added to refluxing soln. of ligand in CHCl3, 5 min, cooled to room temp.; silica gel plug, eluted with CH2Cl2, solvent was evapd.;

DOI:10.1021/ic990914q

upstream raw materials:

pyrrole

mesytaldehyde

2,6-bis[2-(trimethylsilyl)ethynyl]benzaldehyde

zinc diacetate

Downstream raw materials:

Zn(C₄Cl₂N)4(C(C₆HCl(CH₃)3))4

zinc(II) 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetramesitylporphyrin