copper(II) complex of 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin

Base Information

• Chemical Name: copper(II) complex of 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin
• CAS No.: 146343-94-4
• Molecular Formula: C₆₀H₆₀CuN₄
• Molecular Weight: 900.709
• Mol file: 146343-94-4.mol

Synonyms:copper(II) complex of 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin

Chemical Property of copper(II) complex of 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of copper(II) complex of 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin

There total 3 articles about copper(II) complex of 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

copper diacetate (142-71-2) + 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin (63511-61-5) → copper(II) complex of 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin (146343-94-4)

Guidance literature:

In N,N-dimethyl-formamide; at 24.84 ℃;

DOI:10.1134/S1070363217060123

Reference yield:

5,10,15,20-tetraphenyl-2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphyne + copper diacetate (142-71-2) → copper(II) complex of 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin (146343-94-4)

Guidance literature:

In N,N-dimethyl-formamide; Cu-salt was refluxed with ligand in DMF; chromd. on Al2O3 with chloroform;

DOI:10.1023/A:1025673427341

Reference yield:

5,10,15,20-tetraphenyl-2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphyne + copper(II) acetate monohydrate (6046-93-1) → copper(II) complex of 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin (146343-94-4)

Guidance literature:

In N,N-dimethyl-formamide; Cu acetate reacted with porphyrin in boiling DMF; according to A. D. Adler, F. R. Longo, F. Kampas, J. Kim, J. Inorg. Nucl. Chem., 1970, 32, 2443; purified by column chromy. (Al2O3, CHCl3); detd. by TLC;

DOI:10.1007/s11172-007-0112-2

upstream raw materials:

copper(II) acetate monohydrate

copper diacetate

2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin