(1SR,2RS,3RS,4RS,6SR)-2,6-dimethyl-4-(phenylsulfonyl)-4-(2-propenyl)-3-(2-oxopropyl)cyclohexane-1,2-diol 1,2-acetonide dimethylhydrazone

Base Information

Chemical Name:(1SR,2RS,3RS,4RS,6SR)-2,6-dimethyl-4-(phenylsulfonyl)-4-(2-propenyl)-3-(2-oxopropyl)cyclohexane-1,2-diol 1,2-acetonide dimethylhydrazone
CAS No.:82769-91-3
Molecular Formula:C₂₅H₃₈N₂O₄S
Molecular Weight:462.654
Hs Code.:

Synonyms:(1SR,2RS,3RS,4RS,6SR)-2,6-dimethyl-4-(phenylsulfonyl)-4-(2-propenyl)-3-(2-oxopropyl)cyclohexane-1,2-diol 1,2-acetonide dimethylhydrazone

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Chemical Property of (1SR,2RS,3RS,4RS,6SR)-2,6-dimethyl-4-(phenylsulfonyl)-4-(2-propenyl)-3-(2-oxopropyl)cyclohexane-1,2-diol 1,2-acetonide dimethylhydrazone

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Technology Process of (1SR,2RS,3RS,4RS,6SR)-2,6-dimethyl-4-(phenylsulfonyl)-4-(2-propenyl)-3-(2-oxopropyl)cyclohexane-1,2-diol 1,2-acetonide dimethylhydrazone

There total 3 articles about (1SR,2RS,3RS,4RS,6SR)-2,6-dimethyl-4-(phenylsulfonyl)-4-(2-propenyl)-3-(2-oxopropyl)cyclohexane-1,2-diol 1,2-acetonide dimethylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 81939-86-8
trans,cis-3,5-dimethyl-1-phenylthio-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide

: 82769-91-3
(1SR,2RS,3RS,4RS,6SR)-2,6-dimethyl-4-(phenylsulfonyl)-4-(2-propenyl)-3-(2-oxopropyl)cyclohexane-1,2-diol 1,2-acetonide dimethylhydrazone

Guidance literature:: Multi-step reaction with 3 steps

1: 92 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 1 h / Ambient temperature

2: 91 percent / phosphorus oxychloride / pyridine / 3 h / 110 °C

3: 1.) KDA / 1.) THF, -25 deg C, 10 min, 2.) -25 deg C, 10 min

With Diethoxy-methyl-(6-amino-hexylaminomethyl)-silan; 3-chloro-benzenecarboperoxoic acid; trichlorophosphate; In pyridine; dichloromethane;
DOI:10.1021/ja00385a030

Reference yield:

: 82769-82-2
trans,cis-3,5-dimethyl-1-(phenylsulfonyl)-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide

: 82769-91-3
(1SR,2RS,3RS,4RS,6SR)-2,6-dimethyl-4-(phenylsulfonyl)-4-(2-propenyl)-3-(2-oxopropyl)cyclohexane-1,2-diol 1,2-acetonide dimethylhydrazone

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / phosphorus oxychloride / pyridine / 3 h / 110 °C

2: 1.) KDA / 1.) THF, -25 deg C, 10 min, 2.) -25 deg C, 10 min

With Diethoxy-methyl-(6-amino-hexylaminomethyl)-silan; trichlorophosphate; In pyridine;
DOI:10.1021/ja00385a030

Reference yield:

: 13483-31-3
Acetone dimethylhydrazone

: 82769-83-3
cis-3,4-dihydroxy-trans-3,5-dimethyl-1-(phenylsulfonyl)cyclohexene 3,4-acetonide

: 106-95-6
allyl bromide

: 82769-91-3
(1SR,2RS,3RS,4RS,6SR)-2,6-dimethyl-4-(phenylsulfonyl)-4-(2-propenyl)-3-(2-oxopropyl)cyclohexane-1,2-diol 1,2-acetonide dimethylhydrazone

Guidance literature:: With Diethoxy-methyl-(6-amino-hexylaminomethyl)-silan; Yield given. Multistep reaction; 1.) THF, -25 deg C, 10 min, 2.) -25 deg C, 10 min;
DOI:10.1021/ja00385a030