trans,cis-3,5-dimethyl-1-(phenylsulfonyl)-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide

Base Information

Chemical Name:trans,cis-3,5-dimethyl-1-(phenylsulfonyl)-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide
CAS No.:82769-82-2
Molecular Formula:C₁₇H₂₄O₅S
Molecular Weight:340.441
Hs Code.:

Synonyms:trans,cis-3,5-dimethyl-1-(phenylsulfonyl)-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide

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Chemical Property of trans,cis-3,5-dimethyl-1-(phenylsulfonyl)-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide

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Technology Process of trans,cis-3,5-dimethyl-1-(phenylsulfonyl)-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide

There total 1 articles about trans,cis-3,5-dimethyl-1-(phenylsulfonyl)-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 81939-86-8
trans,cis-3,5-dimethyl-1-phenylthio-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide

: 82769-82-2
trans,cis-3,5-dimethyl-1-(phenylsulfonyl)-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 1h; Ambient temperature;
DOI:10.1021/ja00385a030

Reference yield: 91.0%

: 82769-82-2
trans,cis-3,5-dimethyl-1-(phenylsulfonyl)-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide

: 82769-83-3
cis-3,4-dihydroxy-trans-3,5-dimethyl-1-(phenylsulfonyl)cyclohexene 3,4-acetonide

Guidance literature:: With trichlorophosphate; In pyridine; at 110 ℃; for 3h;
DOI:10.1021/ja00385a030

Reference yield:

: 82769-82-2
trans,cis-3,5-dimethyl-1-(phenylsulfonyl)-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide

: 82769-93-5,109668-87-3
(1SR,2RS,3RS,4RS,6SR)-2,6-dimethyl-4-(phenylsulfonyl)-4-(2-propenyl)-3-<3-(methoxycarbonyl)-2-oxopropyl>cyclohexane-1,2-diol 1,2-diacetonide

Guidance literature:: Multi-step reaction with 4 steps

1: 91 percent / phosphorus oxychloride / pyridine / 3 h / 110 °C

2: 1.) KDA / 1.) THF, -25 deg C, 10 min, 2.) -25 deg C, 10 min

3: 84 percent / paraformaldehyde, boron trifluoride etherate / acetone; H₂O / 48 h / 25 °C

4: 78 percent / sodium hydride / methanol; tetrahydrofuran / 2 h / Heating

With formaldehyd; boron trifluoride diethyl etherate; Diethoxy-methyl-(6-amino-hexylaminomethyl)-silan; sodium hydride; trichlorophosphate; In tetrahydrofuran; pyridine; methanol; water; acetone;
DOI:10.1021/ja00385a030