1,1,2,2,2-Pentafluoroethyl hypofluorite

Base Information

• Chemical Name: 1,1,2,2,2-Pentafluoroethyl hypofluorite
• CAS No.: 3848-94-0
• Molecular Formula: C₂F₆O
• Molecular Weight: 154.012
• DSSTox Substance ID: DTXSID301348925
• Mol file: 3848-94-0.mol

Synonyms:1,1,2,2,2-pentafluoroethyl hypofluorite;CF3CF2OF;(Fluorooxy)pentafluoroethane;pentafluoroethyl hypofluorite;SCHEMBL2238876;DTXSID301348925;3848-94-0;hypofluorous acid 1,1,2,2,2-pentafluoro-ethyl ester

Chemical Property of 1,1,2,2,2-Pentafluoroethyl hypofluorite

Chemical Property:

• XLogP3: 2.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 0
• Exact Mass: 153.98533359
• Heavy Atom Count: 9
• Complexity: 93.7

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C(C(F)(F)F)(OF)(F)F

Technology Process of 1,1,2,2,2-Pentafluoroethyl hypofluorite

There total 3 articles about 1,1,2,2,2-Pentafluoroethyl hypofluorite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium 2,2,2-trifluoroacetate (2923-18-4) → hypofluorous acid trifluoromethyl ester (373-91-1) + bis(fluoroxy)difluoromethane (16282-67-0) + pentafluoroethyl oxyfluoride (3848-94-0) + 1,1-Difluoroxy-1,2,2,2-tetrafluorethan (16329-92-3)

Guidance literature:

With fluorine; at 0 ℃; Title compound not separated from byproducts;

DOI:10.1021/jo00359a018

Reference yield:

trichloro-acetic acid-(3-hydroxy-propyl ester) (7297-44-1) → freon-218 (76-19-7) + trichlorofluoromethane (75-69-4) + trifluoroacetyl fluoride (354-34-7) + pentafluoroethyl oxyfluoride (3848-94-0)

Guidance literature:

With fluorine; sodium fluoride; Further byproducts given;

DOI:10.1021/jo01340a010

Reference yield:

sodium 2,2,2-trifluoroacetate (2923-18-4) → pentafluoroethyl oxyfluoride (3848-94-0) + 1,1-Difluoroxy-1,2,2,2-tetrafluorethan (16329-92-3)

Guidance literature:

With fluorine; at -110 ℃; Title compound not separated from byproducts;

DOI:10.1021/jo00359a018

upstream raw materials:

trichloro-acetic acid-(3-hydroxy-propyl ester)

sodium 2,2,2-trifluoroacetate

Downstream raw materials:

erythro-1-Fluoro-2-(pentafluoroethoxy)-1,2-diphenylethane

threo-1-Fluoro-2-(pentafluoroethoxy)-1,2-diphenylethane

threo-1-Fluoro-1-<4'-(carbomethoxy)phenyl>-2-(pentafluoroethoxy)-2-phenylethane

erythro-1-Fluoro-1-<2'-(carbomethoxy)phenyl>-2-(pentafluoroethoxy)-2-phenylethane