Technology Process of {2-(4',4',5',5'-tetramethyl[1',3',2']dioxaborolan-2'-yl)-5,10,15,20-tetraphenylporphyrinato}-nickel(II)
There total 2 articles about {2-(4',4',5',5'-tetramethyl[1',3',2']dioxaborolan-2'-yl)-5,10,15,20-tetraphenylporphyrinato}-nickel(II) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate;
In
water; toluene;
at 110 ℃;
for 3h;
Inert atmosphere;
DOI:10.1021/ja8055886
- Guidance literature:
-
With
potassium acetate;
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride;
In
water; toluene;
(Ar); bromoporphirine, bis(pinacolato)diboron, palladium complex and KOAc were refluxed in toluene and water at 110°C for 3 h; CH2Cl2 was added, washed with water and satd. aq. soln. of NH4Cl, organic layer dried over MgSO4, evapd. in vac., column chromy. (silica gel, petroleum ether/CH2Cl2, 5:1 to 0:1, v/v);
DOI:10.1021/ja8055886
- Guidance literature:
-
With
barium dihydroxide;
tetrakis(triphenylphosphine) palladium(0);
In
water; toluene;
(Ar); toluene and water were added to mixture of boronic ester, bromoporphyrin and Ba(OH)2*8H2O, Pd(PPh3)4 was added, refluxed for 18 h with stirring; CH2Cl2 and H2O were added, aq. phase was extd. with CH2Cl2, combined organic phase was washed with water and satd. aq. soln. of NH4Cl, organic layer dried over MgSO4, evapd. in vac., column chromy. (silica gel, petroleum ether/CH2Cl2, 4:1 to 0:1, v/v);
DOI:10.1021/ja8055886
