methyl 6-S-acetyl-2,3,4-tri-O-benzoyl-α-D-glucopyranoside

Base Information

• Chemical Name: methyl 6-S-acetyl-2,3,4-tri-O-benzoyl-α-D-glucopyranoside
• CAS No.: 686341-62-8
• Molecular Formula: C₃₀H₂₈O₉S
• Molecular Weight: 564.613
• Mol file: 686341-62-8.mol

Synonyms:methyl 6-S-acetyl-2,3,4-tri-O-benzoyl-α-D-glucopyranoside

Chemical Property of methyl 6-S-acetyl-2,3,4-tri-O-benzoyl-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of methyl 6-S-acetyl-2,3,4-tri-O-benzoyl-α-D-glucopyranoside

There total 1 articles about methyl 6-S-acetyl-2,3,4-tri-O-benzoyl-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

methyl 2,3,4-tri-O-benzoylglucopyranoside (34234-44-1) + tiolacetic acid (507-09-5) → methyl 6-S-acetyl-2,3,4-tri-O-benzoyl-α-D-glucopyranoside (686341-62-8)

Guidance literature:

With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; at 20 ℃; for 13h;

DOI:10.1021/ja031895t

Reference yield: 82.0%

methyl 6-S-acetyl-2,3,4-tri-O-benzoyl-α-D-glucopyranoside (686341-62-8) → methyl 2,3,4-tri-O-benzoyl-6-deoxy-α-D-glucopyranoside (51236-53-4)

Guidance literature:

methyl 6-S-acetyl-2,3,4-tri-O-benzoyl-α-D-glucopyranoside; With hydrazine hydrate; In N,N-dimethyl-formamide; at 20 ℃; for 0.0666667h;

With tris-(2-carboxyethyl)-phosphine hydrochloride; In N,N-dimethyl-formamide; at 20 ℃; for 1h; UV-irradiation; Molecular sieve;

DOI:10.1021/acs.orglett.9b02033

Reference yield: 56.0%

methyl 6-S-acetyl-2,3,4-tri-O-benzoyl-α-D-glucopyranoside (686341-62-8) → 2,3,4-tri-O-benzoyl-6-thio-α-methyl-D-glucopyranoside (686341-49-1)

Guidance literature:

methyl 6-S-acetyl-2,3,4-tri-O-benzoyl-α-D-glucopyranoside; With hydrazine hydrate; In N,N-dimethyl-formamide; at 20 ℃; for 0.166667h;

With acetic acid; In N,N-dimethyl-formamide; at 20 ℃; for 0.5h;

DOI:10.1021/ja031895t

upstream raw materials:

methyl 2,3,4-tri-O-benzoylglucopyranoside

tiolacetic acid

Downstream raw materials:

2,3,4-tri-O-benzoyl-6-thio-α-methyl-D-glucopyranoside

methyl 2,3,4-tri-O-benzoyl-6-deoxy-α-D-glucopyranoside