[RuH(CO)(P(OEt)3)4]BPh₄

Base Information

Chemical Name:[RuH(CO)(P(OEt)3)4]BPh₄
CAS No.:870714-96-8
Molecular Formula:C₂₄H₂₀B*C₂₅H₆₁O₁₃P₄Ru
Molecular Weight:1113.95
Hs Code.:

Synonyms:[RuH(CO)(P(OEt)3)4]BPh₄

Suppliers and Price of [RuH(CO)(P(OEt)3)4]BPh₄

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [RuH(CO)(P(OEt)3)4]BPh₄

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [RuH(CO)(P(OEt)3)4]BPh₄

There total 1 articles about [RuH(CO)(P(OEt)3)4]BPh₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 38720-12-6
RuH₂(P(OEt)3)4

: 201230-82-2
carbon monoxide

: 143-66-8
sodium tetraphenyl borate

: 870714-96-8
[RuH(CO)(P(OEt)3)4]BPh₄

Guidance literature:: With triflic acid; In ethanol; under inert atm. triflic acid was added to soln. RuH2(P(OEt)3)4 in EtOH at -196°C, placed under CO atm (1 atm) and stirred for 2 h at room temp., solvent was removed in vacuo, residue was triturated with EtOH with NaBPh4; ppt. was filtered and crystd. from CH2Cl2-EtOH; elem. anal.;
DOI:10.1021/ic050817z

Reference yield:

: 870714-96-8
[RuH(CO)(P(OEt)3)4]BPh₄

: 143-66-8
sodium tetraphenyl borate

: 302-01-2,78206-91-4,119775-10-9,75013-58-0
hydrazine

: [Ru(CO)(NH₂NH₂)(P(OEt)3)4](BPh₄)2

Guidance literature:: With HBF₄*Et₂O; In diethyl ether; dichloromethane; under inert atm. HBF4*Et2O in Et2O was added to soln. Ru complex in CH2Cl2 at -196°C, hydrazine was added, brought to room temp. and stirred for 24 h, solvent was removed in vacuo and triturated with NaBPh4 inEtOH; ppt. was filtered and crystd. from CH2Cl2-EtOH; elem. anal.;
DOI:10.1021/ic050817z

Reference yield:

: 870714-96-8
[RuH(CO)(P(OEt)3)4]BPh₄

: 143-66-8
sodium tetraphenyl borate

: 100-63-0
phenylhydrazine

: [Ru(CO)(NH₂NHPh)(P(OEt)3)4](BPh₄)2

Guidance literature:: With HBF₄*Et₂O; In diethyl ether; dichloromethane; under inert atm. HBF4*Et2O in Et2O was added to soln. Ru complex in CH2Cl2 at -196°C, hydrazine was added, brought to room temp. and stirred for 24 h, solvent was removed in vacuo and triturated with NaBPh4 inEtOH; ppt. was filtered and crystd. from CH2Cl2-EtOH; elem. anal.;
DOI:10.1021/ic050817z