pentacarbonyl[2-(bis(trimethylsilyl)methyl)-3-phenyl-2H-azaphosphirene-κP]molybdenum(0)

Base Information

Chemical Name:pentacarbonyl[2-(bis(trimethylsilyl)methyl)-3-phenyl-2H-azaphosphirene-κP]molybdenum(0)
CAS No.:207723-64-6
Molecular Formula:C₁₉H₂₄MoNO₅PSi₂
Molecular Weight:529.488
Hs Code.:

Synonyms:pentacarbonyl[2-(bis(trimethylsilyl)methyl)-3-phenyl-2H-azaphosphirene-κP]molybdenum(0)

Suppliers and Price of pentacarbonyl[2-(bis(trimethylsilyl)methyl)-3-phenyl-2H-azaphosphirene-κP]molybdenum(0)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of pentacarbonyl[2-(bis(trimethylsilyl)methyl)-3-phenyl-2H-azaphosphirene-κP]molybdenum(0)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of pentacarbonyl[2-(bis(trimethylsilyl)methyl)-3-phenyl-2H-azaphosphirene-κP]molybdenum(0)

There total 2 articles about pentacarbonyl[2-(bis(trimethylsilyl)methyl)-3-phenyl-2H-azaphosphirene-κP]molybdenum(0) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: pentacarbonyl[amino(phenyl)carbene]molybdenum⁽⁰⁾

: 79454-85-6
[bis(trimethylsilyl)methylene]chlorophosphane

: 207723-64-6
pentacarbonyl[2-(bis(trimethylsilyl)methyl)-3-phenyl-2H-azaphosphirene-κP]molybdenum(0)

Guidance literature:: With NEt₃; In diethyl ether; byproducts: [C2H5)3NH]l; N2 atmosphere, addn. of chlorophosphane and N(C2H5)3 to soln. of Mo complex at -10°C, stirring 48 h, slow warming to room temp.; evapn. to dryness (0.1 mbar), extn. (pentane), filtration, washing of filtration residues (pentane), removement of solvent of organic phases (reduced pressure), column chromy. (SiO2, -15°C, hexane/ether (9:1)), removement of solvent; elem. anal.;
DOI:10.1002/(SICI)1099-0682(199805)1998:5<571::AID-EJIC571>3.0.CO;2-9

Reference yield:

: pentacarbonyl[amino(phenyl)carbene]molybdenum⁽⁰⁾

: 79454-85-6
[bis(trimethylsilyl)methylene]chlorophosphane

: 121-44-8
triethylamine

: 207723-64-6
pentacarbonyl[2-(bis(trimethylsilyl)methyl)-3-phenyl-2H-azaphosphirene-κP]molybdenum(0)

: 554-68-7
triethylamine hydrochloride

Guidance literature:: In diethyl ether; for 24h; Inert atmosphere; Schlenk technique;
DOI:10.1021/ic302786v

Reference yield: 89.0%

: 207723-64-6
pentacarbonyl[2-(bis(trimethylsilyl)methyl)-3-phenyl-2H-azaphosphirene-κP]molybdenum(0)

: 1493-13-6
trifluorormethanesulfonic acid

: 1467-79-4
NCNMe₂

: 1313434-04-6
[2-bis(trimethylsilyl)methyl-5-dimethylamino-3-phenyl-2H-1,4,2-diazaphosphole-κP]pentacarbonylmolybdenum(0)

Guidance literature:: With N(C₂H₅)3; In dichloromethane; byproducts: [(C2H5)3NH][CF3SO3]; (Ar, Schlenk technique); addn. of dimethylcyanamide and then triflic acid to CH2Cl2 soln. of molybdenum compd. at -30°C, keeping for 2 min, addn. of triethylamine; evapn., chromy. (silica, petroleum ether/diethyl ether (100:1)) at -30°C, evapn., elem. anal.;
DOI:10.1016/j.poly.2011.04.014