DIIODO(1,5-CYCLOOCTADIENE)PLATINUM (II)

Base Information

• Chemical Name: DIIODO(1,5-CYCLOOCTADIENE)PLATINUM (II)
• CAS No.: 12266-72-7
• Molecular Formula: C8H12 I2 Pt
• Molecular Weight: 557.072
• European Community (EC) Number: 235-538-7
• Mol file: 12266-72-7.mol

Synonyms:Platinum,(1,5-cyclooctadiene)diiodo- (8CI); Platinum, diiodo(1,5-cyclooctadiene)- (7CI);1,5-Cyclooctadiene, platinum complex; (1,5-Cyclooctadiene)diiodoplatinum;(Cyclooctadiene)diiodoplatinum; Diiodo(cyclooctadiene)platinum

Chemical Property of DIIODO(1,5-CYCLOOCTADIENE)PLATINUM (II)

Chemical Property:

• Vapor Pressure: 4.25mmHg at 25°C
• Melting Point: 260°C (dec.)
• Boiling Point: 153.5°Cat760mmHg
• Flash Point: 31.7°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 4.44170
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 556.86764
• Heavy Atom Count: 11
• Complexity: 75.4

Purity/Quality:

97% ^*data from raw suppliers

Diiodo(1,5-cyclooctadiene)platinum(II), 99% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CC=CCCC=C1.I[Pt]I
• Isomeric SMILES: C1/C=C\CC/C=C\C1.I[Pt]I
• Uses: It is applied as an organic intermediate.

Technology Process of DIIODO(1,5-CYCLOOCTADIENE)PLATINUM (II)

There total 10 articles about DIIODO(1,5-CYCLOOCTADIENE)PLATINUM (II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) + sodium iodide (7681-82-5,24359-64-6,41927-88-2,115813-40-6) → 1,5-cyclooctadienediiodoplatinum(II) (12266-72-7)

Guidance literature:

In acetone; at 21 ℃; for 3h;

DOI:10.1002/cmdc.202100157

Reference yield: 90.0%

potassium tetrachloroplatinate(II) (10025-99-7) + potassium iodide (7681-11-0) + cyclo-octa-1,5-diene (5259-72-3,10060-40-9,111-78-4) → 1,5-cyclooctadienediiodoplatinum(II) (12266-72-7)

Guidance literature:

In water; acetic acid; solid KI was added to aq. soln. of Pt complex; acetic acid and diene were added; left at 80°C for 2 h; cooled; filtered; washed (H2O, EtOH, (i-Pr)2O); dried (vac.); elem. anal.;

DOI:10.1021/ic901510m

Reference yield:

(C5(CH3)5)Pt(C8H12(C5(CH3)5)) (108818-18-4) → (1,5-cylooctadiene)di-iodoplatinum(II) (12266-72-7)

Guidance literature:

With iodine; In not given;

upstream raw materials:

dichloro(1,5-cyclooctadiene)platinum(ll)

sodium iodide

{bis(pentafluorophenyl)platinum(μ-I)2platinum(η4-1,5-cyclooctadiene)}

(C₅(CH₃)5)Pt(C₈H₁₂(C₅(CH₃)5))

Downstream raw materials:

{bis(pentachlorophenyl)platinum(μ-I)2platinum(η4-1,5-cyclooctadiene)}

{bis(pentafluorophenyl)platinum(μ-I)2platinum(η4-1,5-cyclooctadiene)}

cis-diiodo{bis(dicyclohexylphosphino)ethane}platinumm(II)

cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum

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