Benzenesulfonamide, N-2-(acetyloxy)methyl-4-(benzoyloxy)-3,5-dihydroxycyclopentyl-4-methyl-, 1S-(1.alpha.,2.beta.,3.alpha.,4.beta.,5.alpha.)-

Base Information

Chemical Name:Benzenesulfonamide, N-2-(acetyloxy)methyl-4-(benzoyloxy)-3,5-dihydroxycyclopentyl-4-methyl-, 1S-(1.alpha.,2.beta.,3.alpha.,4.beta.,5.alpha.)-
CAS No.:165375-24-6
Molecular Formula:C₂₂H₂₅NO₈S
Molecular Weight:463.508
Hs Code.:
Mol file:165375-24-6.mol

Synonyms:Benzenesulfonamide, N-2-(acetyloxy)methyl-4-(benzoyloxy)-3,5-dihydroxycyclopentyl-4-methyl-, 1S-(1.alpha.,2.beta.,3.alpha.,4.beta.,5.alpha.)-

Suppliers and Price of Benzenesulfonamide, N-2-(acetyloxy)methyl-4-(benzoyloxy)-3,5-dihydroxycyclopentyl-4-methyl-, 1S-(1.alpha.,2.beta.,3.alpha.,4.beta.,5.alpha.)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Benzenesulfonamide, N-2-(acetyloxy)methyl-4-(benzoyloxy)-3,5-dihydroxycyclopentyl-4-methyl-, 1S-(1.alpha.,2.beta.,3.alpha.,4.beta.,5.alpha.)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Benzenesulfonamide, N-2-(acetyloxy)methyl-4-(benzoyloxy)-3,5-dihydroxycyclopentyl-4-methyl-, 1S-(1.alpha.,2.beta.,3.alpha.,4.beta.,5.alpha.)-

There total 8 articles about Benzenesulfonamide, N-2-(acetyloxy)methyl-4-(benzoyloxy)-3,5-dihydroxycyclopentyl-4-methyl-, 1S-(1.alpha.,2.beta.,3.alpha.,4.beta.,5.alpha.)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

: 127-65-1
chloroamine-T

: 165375-15-5
Benzoic acid (1R,4R,5R)-5-acetoxy-4-hydroxymethyl-cyclopent-2-enyl ester

: 165375-23-5
Benzoic acid (1R,2R,3R,4S,5S)-2-acetoxy-5-hydroxy-3-hydroxymethyl-4-(toluene-4-sulfonylamino)-cyclopentyl ester

: 165375-24-6
Benzoic acid (1S,2R,3R,4S,5S)-3-acetoxymethyl-2,5-dihydroxy-4-(toluene-4-sulfonylamino)-cyclopentyl ester

: 165375-17-7
Benzoic acid (1R,2R,3S,4S,5S)-3-acetoxymethyl-2,4-dihydroxy-5-(toluene-4-sulfonylamino)-cyclopentyl ester

Guidance literature:: With osmium(VIII) oxide; In tert-butyl alcohol; at 45 ℃; for 40h; Yields of byproduct given;

Reference yield:

: 54497-89-1
methyl 2,6-bis-α-D-glucopyranoside

: 165375-24-6
Benzoic acid (1S,2R,3R,4S,5S)-3-acetoxymethyl-2,5-dihydroxy-4-(toluene-4-sulfonylamino)-cyclopentyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: 55 percent / pyridine / 1.) 0 deg C, 7 h, 2.) 20 deg C, 30 h

2: 86 percent / pyridine / 1 h / 20 °C

3: 83 percent / NaI / acetic anhydride / 1 h / Heating

4: Zn / ethanol / Heating

5: 57 percent / ethanol; pyridine / 1.6 h / 45 °C

6: 68 percent / H₂ / Raney nickel

7: 81 percent / magnesium monoperoxyphthalate hexahydrate / propan-2-ol

8: OsO₄ / 2-methyl-propan-2-ol / 40 h / 45 °C

With osmium(VIII) oxide; hydrogen; magnesium monoperoxyphthalate hexahydrate; sodium iodide; zinc; nickel; In pyridine; ethanol; acetic anhydride; isopropyl alcohol; tert-butyl alcohol;

Reference yield:

: 165375-12-2
Benzoic acid (1S,2R)-2-acetoxy-1-[(R)-2-oxo-1-(toluene-4-sulfonyloxy)-ethyl]-but-3-enyl ester

: 165375-24-6
Benzoic acid (1S,2R,3R,4S,5S)-3-acetoxymethyl-2,5-dihydroxy-4-(toluene-4-sulfonylamino)-cyclopentyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 57 percent / ethanol; pyridine / 1.6 h / 45 °C

2: 68 percent / H₂ / Raney nickel

3: 81 percent / magnesium monoperoxyphthalate hexahydrate / propan-2-ol

4: OsO₄ / 2-methyl-propan-2-ol / 40 h / 45 °C

With osmium(VIII) oxide; hydrogen; magnesium monoperoxyphthalate hexahydrate; nickel; In pyridine; ethanol; isopropyl alcohol; tert-butyl alcohol;