Benzenesulfonamide, N-3-(acetyloxy)methyl-5-(benzoyloxy)-2,4-dihydroxycyclopentyl-4-methyl-, 1S-(1.alpha.,2.alpha.,3.beta.,4.alpha.,5.beta.)-

Base Information

• Chemical Name: Benzenesulfonamide, N-3-(acetyloxy)methyl-5-(benzoyloxy)-2,4-dihydroxycyclopentyl-4-methyl-, 1S-(1.alpha.,2.alpha.,3.beta.,4.alpha.,5.beta.)-
• CAS No.: 165375-17-7
• Molecular Formula: C₂₂H₂₅NO₈S
• Molecular Weight: 463.508
• Mol file: 165375-17-7.mol

Synonyms:Benzenesulfonamide, N-3-(acetyloxy)methyl-5-(benzoyloxy)-2,4-dihydroxycyclopentyl-4-methyl-, 1S-(1.alpha.,2.alpha.,3.beta.,4.alpha.,5.beta.)-

Chemical Property of Benzenesulfonamide, N-3-(acetyloxy)methyl-5-(benzoyloxy)-2,4-dihydroxycyclopentyl-4-methyl-, 1S-(1.alpha.,2.alpha.,3.beta.,4.alpha.,5.beta.)-

Chemical Property:

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Technology Process of Benzenesulfonamide, N-3-(acetyloxy)methyl-5-(benzoyloxy)-2,4-dihydroxycyclopentyl-4-methyl-, 1S-(1.alpha.,2.alpha.,3.beta.,4.alpha.,5.beta.)-

There total 1 articles about Benzenesulfonamide, N-3-(acetyloxy)methyl-5-(benzoyloxy)-2,4-dihydroxycyclopentyl-4-methyl-, 1S-(1.alpha.,2.alpha.,3.beta.,4.alpha.,5.beta.)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

chloroamine-T (127-65-1) + Benzoic acid (1R,4R,5R)-5-acetoxy-4-hydroxymethyl-cyclopent-2-enyl ester (165375-15-5) → Benzoic acid (1R,2R,3R,4S,5S)-2-acetoxy-5-hydroxy-3-hydroxymethyl-4-(toluene-4-sulfonylamino)-cyclopentyl ester (165375-23-5) + Benzoic acid (1S,2R,3R,4S,5S)-3-acetoxymethyl-2,5-dihydroxy-4-(toluene-4-sulfonylamino)-cyclopentyl ester (165375-24-6) + Benzoic acid (1R,2R,3S,4S,5S)-3-acetoxymethyl-2,4-dihydroxy-5-(toluene-4-sulfonylamino)-cyclopentyl ester (165375-17-7)

Guidance literature:

With osmium(VIII) oxide; In tert-butyl alcohol; at 45 ℃; for 40h; Yields of byproduct given;

upstream raw materials:

chloroamine-T

Benzoic acid (1R,4R,5R)-5-acetoxy-4-hydroxymethyl-cyclopent-2-enyl ester

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