trans-3-Methoxy-1-propenylboronic acid pinacol ester

Base Information

Chemical Name:trans-3-Methoxy-1-propenylboronic acid pinacol ester
CAS No.:165059-42-7
Molecular Formula:C10H19 B O3
Molecular Weight:198.07
Hs Code.:2931900090
European Community (EC) Number:626-097-5
Nikkaji Number:J2.359.555I,J730.121I
Wikidata:Q76511202
Mol file:165059-42-7.mol

Synonyms:165059-42-7;trans-3-Methoxy-1-propenylboronic acid pinacol ester;(E)-2-(3-METHOXYPROP-1-EN-1-YL)-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE;(E)-3-METHOXY-1-PROPEN-1-YLBORONIC ACID, PINACOL ESTER;2-[(E)-3-methoxyprop-1-enyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;(E)-3-Methoxy-1-propen-1-ylboronic acid,pinacol ester;2-(3-methoxyprop-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;2-[(1E)-3-METHOXYPROP-1-EN-1-YL]-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE;MFCD05664297;FBAOFKFCKHJXRU-VOTSOKGWSA-N;(E)-2-(3-Methoxy-1-propen-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;SCHEMBL478114;SCHEMBL478116;AKOS017343602;BS-22574;CS-0129099;H10918;EN300-1440080;J-010178;(E)-3-Methoxy-1-propen-1-ylboronic acid pinacol ester;Z1255387464;trans-3-Methoxy-1-propenylboronic acid pinacol ester, 95%;(E)-2-(3-Methoxypropenyl)4,4,5,5-tetramethyl-1,3,2-dioxaborolane;(E)-2-(3-methoxyprop-1-enyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;(E)-2-(3-methoxypropenyl)-4,4,5,5,-tetramethyl-(1,3,2)-dioxaborolane;(E)-2-(3-Methoxypropenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;2-((E)-3-methoxy-propenyl)-4,4,5,5-tetramethyl[1,3,2]dioxaborolane;4,4,5,5-tetramethyl-2-[(1E)-3-(methyl oxy)-1-propen-1-yl]-1,3,2-dioxaborolane;4,4,5,5-tetramethyl-2-[(1E)-3-(methyloxy)-1-propen-1-yl]-1,3,2-dioxaborolane

Suppliers and Price of trans-3-Methoxy-1-propenylboronic acid pinacol ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(E)-3-Methoxy-1-Propen-1-YlboronicAcid,PinacolEster
500mg
$ 200.00

Sigma-Aldrich
trans-3-Methoxy-1-propenylboronic acid pinacol ester 95%
1g
$ 70.40

Sigma-Aldrich
trans-3-Methoxy-1-propenylboronic acid pinacol ester 95%
10g
$ 385.00

Crysdot
(E)-2-(3-Methoxyprop-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 95+%
10g
$ 400.00

American Custom Chemicals Corporation
TRANS-3-METHOXY-1-PROPENYLBORONIC ACID PINACOL ESTER 95.00%
10G
$ 1399.51

American Custom Chemicals Corporation
TRANS-3-METHOXY-1-PROPENYLBORONIC ACID PINACOL ESTER 95.00%
1G
$ 253.05

Total 18 raw suppliers

Chemical Property of trans-3-Methoxy-1-propenylboronic acid pinacol ester

Chemical Property:

Vapor Pressure:0.279mmHg at 25°C
Refractive Index:n20/D 1.4430(lit.)
Boiling Point:229-230 °C(lit.)
Flash Point:214 °F
PSA：27.69000
Density:0.933 g/mL at 25 °C(lit.)
LogP:1.82040
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:198.1427246
Heavy Atom Count:14
Complexity:207

Purity/Quality:

98%,99%, ^*data from raw suppliers

(E)-3-Methoxy-1-Propen-1-YlboronicAcid,PinacolEster ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C=CCOC
Isomeric SMILES:B1(OC(C(O1)(C)C)(C)C)/C=C/COC

Technology Process of trans-3-Methoxy-1-propenylboronic acid pinacol ester

There total 6 articles about trans-3-Methoxy-1-propenylboronic acid pinacol ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 627-41-8
propargyl alcohol methyl ether

: 165059-42-7,934342-48-0
(E)-3-methoxy-1-propenylboronic acid pinacol ester

Guidance literature:: With bis(cyclohexanyl)borane; at 20 ℃; for 4h;
DOI:10.1055/s-2004-829165

Reference yield: 50.0%

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 627-41-8
propargyl alcohol methyl ether

: 165059-42-7,934342-48-0
2-(3-methoxy-propenyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

Guidance literature:: propargyl alcohol methyl ether; With Schwartz's reagent; at 20 ℃; for 0.5h; Sealed tube; Inert atmosphere;

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; In dichloromethane-d2; at 60 ℃; Sealed tube; Inert atmosphere;

With boron trifluoride diethyl etherate; In dichloromethane-d2; at 20 ℃; for 1h; Sealed tube; Inert atmosphere;
DOI:10.1021/acs.orglett.7b01778

Reference yield: 43.0%

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 627-41-8
propargyl alcohol methyl ether

: 126689-01-8
cyclopropylboronic acid pinacol ester

: 165059-42-7,934342-48-0
2-(3-methoxy-propenyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

Guidance literature:: propargyl alcohol methyl ether; With Schwartz's reagent; at 20 ℃; for 0.5h; Sealed tube; Inert atmosphere;

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; In dichloromethane-d2; at 60 ℃; Sealed tube; Inert atmosphere;

With boron trifluoride diethyl etherate; In dichloromethane-d2; at 20 ℃; for 1h; Sealed tube; Inert atmosphere;
DOI:10.1021/acs.orglett.7b01778