(S,S)-1-(Dicyclohexylphosphino)-2-[1-(diphenylphosphino)ethyl]ferrocene

Base Information

• Chemical Name: (S,S)-1-(Dicyclohexylphosphino)-2-[1-(diphenylphosphino)ethyl]ferrocene
• CAS No.: 162291-01-2
• Molecular Formula: C₃₆H₄₄FeP₂
• Molecular Weight: 594.54
• Hs Code.: 29319090
• European Community (EC) Number: 813-341-2
• Mol file: 162291-01-2.mol

Synonyms:162291-01-2;(S,S)-1-(DICYCLOHEXYLPHOSPHINO)-2-[1-(DIPHENYLPHOSPHINO)ETHYL]FERROCENE;cyclopentane;dicyclohexyl-[2-[(1S)-1-diphenylphosphanylethyl]cyclopentyl]phosphane;iron;(S)-(+)-1-[(R)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDIPHENYLPHOSPHINE;(1S)-1-(DICYCLOHEXYLPHOSPHINO)-2-[(1S)-1-(DIPHENYLPHOSPHINO)ETHYL]FERROCENE;MFCD00800281;(S)-1-[(Rp)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine, >=97%;(S)-1-[(Rp)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine, >=97.0% (CHN/NMR)

Chemical Property of (S,S)-1-(Dicyclohexylphosphino)-2-[1-(diphenylphosphino)ethyl]ferrocene

Chemical Property:

• PSA: 27.18000
• LogP: 9.12070
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 7
• Exact Mass: 594.226761
• Heavy Atom Count: 39
• Complexity: 527

Purity/Quality:

98%,99%, ^*data from raw suppliers

(S)-(+)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine, min. 97% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC([C]1[CH][CH][CH][C]1P(C2CCCCC2)C3CCCCC3)P(C4=CC=CC=C4)C5=CC=CC=C5.[CH]1[CH][CH][CH][CH]1.[Fe]
• Isomeric SMILES: C[C@@H]([C]1[CH][CH][CH][C]1P(C2CCCCC2)C3CCCCC3)P(C4=CC=CC=C4)C5=CC=CC=C5.[CH]1[CH][CH][CH][CH]1.[Fe]

Technology Process of (S,S)-1-(Dicyclohexylphosphino)-2-[1-(diphenylphosphino)ethyl]ferrocene

There total 1 articles about (S,S)-1-(Dicyclohexylphosphino)-2-[1-(diphenylphosphino)ethyl]ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

diphenyl(1-ferrocenylethyl)phosphine + chlorodicyclohexylphosphane (16523-54-9) → 1-(dicyclohexylphosphino)-2-(1-(diphenylphosphino)ethyl)ferrocene (158923-09-2,162291-01-2,223390-59-8,741281-75-4,741281-76-5)

Guidance literature:

diphenyl(1-ferrocenylethyl)phosphine; With n-butyllithium; In tetrahydrofuran; pentane; at -78 - 20 ℃; for 1.5h; Inert atmosphere;

chlorodicyclohexylphosphane; In tetrahydrofuran; pentane; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1016/j.tet.2016.11.054

Reference yield: 86.0%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + 1-(dicyclohexylphosphino)-2-(1-(diphenylphosphino)ethyl)ferrocene (158923-09-2,162291-01-2,223390-59-8,741281-75-4,741281-76-5) + benzonitrile (100-47-0) → C43H49FeNNiP2

Guidance literature:

In toluene; at 20 ℃; for 1h; Inert atmosphere; Glovebox;

DOI:10.1002/anie.201500404

Reference yield: 63.0%

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + 1-(dicyclohexylphosphino)-2-(1-(diphenylphosphino)ethyl)ferrocene (158923-09-2,162291-01-2,223390-59-8,741281-75-4,741281-76-5) + dichloromethane (75-09-2) → (C5H5)Fe(C5H3(CH(CH3)P(C6H5)2)P(C6H11)2)PdCl2*0.5CH2Cl2

Guidance literature:

In dichloromethane; under Ar atm. Pd complex and ligand in CH2Cl2 were stirred for 24 h; soln. was filtered and evapd. in vacuo, residue was washed with Et2O anddried in vacuo; elem. anal.;

DOI:10.1016/j.jorganchem.2007.02.039

upstream raw materials:

chlorodicyclohexylphosphane

Downstream raw materials:

C₃₆H₄₄BrCuFeP₂

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 162291-01-2 (S,S)-1-(DICYCLOHEXYLPHOSPHINO)-2-[1-(DIPHENYLPHOSPHINO)ETHYL]FERROCENE

Send

Send

Metric Ton KG G Pound L ML

Send

Send