(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)palladium(II) acetate

Base Information

• Chemical Name: (2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)palladium(II) acetate
• CAS No.: 152506-88-2
• Molecular Formula: C₃₀H₂₆N₂O₄Pd
• Molecular Weight: 584.967
• Mol file: 152506-88-2.mol

Synonyms:(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)palladium(II) acetate

Chemical Property of (2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)palladium(II) acetate

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)palladium(II) acetate

There total 9 articles about (2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)palladium(II) acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

Bathocuproine (4733-39-5) + palladium diacetate (3375-31-3) → (2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)palladium(II) acetate (152506-88-2)

Guidance literature:

With air; In dichloromethane; at 20 ℃;

DOI:10.1021/jacs.0c09464

Reference yield: 73.0%

[(bathocuproine)Pd(O2)] (358625-60-2) + acetic acid (64-19-7,77671-22-8) → (2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)palladium(II) acetate (152506-88-2) + dihydrogen peroxide (7722-84-1)

Guidance literature:

In dichloromethane-d2; mixing palladium complex with acetic acid in CD2Cl2 in NMR tube for 5 min; detected by NMR;

DOI:10.1021/ja015683c

Reference yield:

[(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)Pd(η2-2-chloro-1,4-benzoquinone)] + acetic acid (64-19-7,77671-22-8) → (2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)palladium(II) acetate (152506-88-2) + chloro-p-hydroquinone (615-67-8)

Guidance literature:

In chloroform-d1; tetradeuterioacetic acid; at 20 ℃; for 16h; Equilibrium constant; Inert atmosphere; Glovebox;

DOI:10.1021/jacs.0c09464

upstream raw materials:

[(bathocuproine)Pd(O₂)]

acetic acid

Bathocuproine

palladium diacetate

Downstream raw materials:

2-Methyl-1,4-benzoquinone

p-benzoquinone

[(CHOO)2(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)palladium(II)]