[(5,10,15-tris(pentafluorophenyl)corrole)Mn(N-p-toluenesulfonate)]

Base Information

• Chemical Name: [(5,10,15-tris(pentafluorophenyl)corrole)Mn(N-p-toluenesulfonate)]
• CAS No.: 918776-48-4
• Molecular Formula: C₄₄H₁₅F₁₅MnN₅O₂S
• Molecular Weight: 1017.62
• Mol file: 918776-48-4.mol

Synonyms:[(5,10,15-tris(pentafluorophenyl)corrole)Mn(N-p-toluenesulfonate)]

Chemical Property of [(5,10,15-tris(pentafluorophenyl)corrole)Mn(N-p-toluenesulfonate)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(5,10,15-tris(pentafluorophenyl)corrole)Mn(N-p-toluenesulfonate)]

There total 2 articles about [(5,10,15-tris(pentafluorophenyl)corrole)Mn(N-p-toluenesulfonate)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-(tert-butylsulfonyl)benzeneI=N-p-toluenesulfonyl + Mn(5,10,15-tris(pentafluorophenyl)corrole(3-))EtOAc*EtOAc (918776-47-3) → (5,10,15-tris(pentafluorophenyl)corrole(3-))Mn(V)=NTs (918776-48-4)

Guidance literature:

In dichloromethane; room temp.;

DOI:10.1021/ja0665489

Reference yield:

manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate (262280-87-5) + [N-(p-toluenesulfonyl)imino](2-tert-butylsulfonyl)phenyliodinane (242461-31-0) → [(5,10,15-tris(pentafluorophenyl)corrole)Mn(N-p-toluenesulfonate)] (918776-48-4)

Guidance literature:

In benzene; byproducts: CH3)3CSO2C6H4I; (Ar); glovebox or Schlenk technique; t-BuSO2C6H4INSO2C6H4CH3 was added to soln. of Mn complex in C6H6;

DOI:10.1021/ja073027s

Reference yield:

[(5,10,15-tris(pentafluorophenyl)corrole)Mn(N-p-toluenesulfonate)] (918776-48-4) → manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate (262280-87-5)

Guidance literature:

With 4-MeO-2,6-t-Bu₂C₆H₂OH; In benzene; byproducts: H2NSO2C6H4CH3, 4-MeO-2,6-t-Bu2C6H2O; (N2); glovebox or Schlenk technique; phenol was added to soln. of Mn complex in C6H6; UV monitoring; not isolated; Kinetics;

DOI:10.1021/ja073027s

upstream raw materials:

Mn(5,10,15-tris(pentafluorophenyl)corrole^(3-))EtOAc*EtOAc

manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate

[N-(p-toluenesulfonyl)imino](2-tert-butylsulfonyl)phenyliodinane

Downstream raw materials:

5,10,15-tris(pentafluorophenyl)corrolato(oxo)manganese(V)

5,10,15-tris(pentafluorophenyl)corrolato-manganese(III)

manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate