[N-(p-toluenesulfonyl)imino](2-tert-butylsulfonyl)phenyliodinane

Base Information

• Chemical Name: [N-(p-toluenesulfonyl)imino](2-tert-butylsulfonyl)phenyliodinane
• CAS No.: 242461-31-0
• Molecular Formula: C₁₇H₂₀INO₄S₂
• Molecular Weight: 493.387
• Mol file: 242461-31-0.mol

Synonyms:[N-(p-toluenesulfonyl)imino](2-tert-butylsulfonyl)phenyliodinane

Chemical Property of [N-(p-toluenesulfonyl)imino](2-tert-butylsulfonyl)phenyliodinane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of [N-(p-toluenesulfonyl)imino](2-tert-butylsulfonyl)phenyliodinane

There total 2 articles about [N-(p-toluenesulfonyl)imino](2-tert-butylsulfonyl)phenyliodinane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

toluene-4-sulfonamide (70-55-3) + 2-(tert-butylsulfonyl)(diacetoxyiodo)benzene (242461-30-9) → [N-(p-toluenesulfonyl)imino](2-tert-butylsulfonyl)phenyliodinane (242461-31-0)

Guidance literature:

With potassium hydroxide; In methanol;

DOI:10.1021/ja991094j

Reference yield:

1-(tert-butylsulfonyl)-2-iodobenzene (69649-28-1) → [N-(p-toluenesulfonyl)imino](2-tert-butylsulfonyl)phenyliodinane (242461-31-0)

Guidance literature:

Multi-step reaction with 2 steps

1: H₂O₂

2: 78 percent / KOH / methanol

With potassium hydroxide; dihydrogen peroxide; In methanol;

DOI:10.1021/ja991094j

Reference yield: 76.0%

toluene (108-88-3,15644-74-3,16713-13-6) + [N-(p-toluenesulfonyl)imino](2-tert-butylsulfonyl)phenyliodinane (242461-31-0) → N-benzyl-p-toluenesulfonamide (1576-37-0)

Guidance literature:

With C₃₈H₃₀CuN₆⁽¹⁺⁾*F₆P^(1-); In chlorobenzene; at 20 ℃; for 24h; Reagent/catalyst; Molecular sieve; Inert atmosphere;

DOI:10.1002/anie.201713171

upstream raw materials:

toluene-4-sulfonamide

2-(tert-butylsulfonyl)(diacetoxyiodo)benzene

1-(tert-butylsulfonyl)-2-iodobenzene

Downstream raw materials:

[(5,10,15-tris(pentafluorophenyl)corrole)Mn(N-p-toluenesulfonate)]

[(5,10,15-tris(pentafluorophenyl)corrole)Mn^IV]⁺

N-(6-(tert-butyldimethylsilyloxy)-1-(2-oxooxazolidin-3-yl)hex-2-enylidene)-4-methylbenzenesulfonamide

S-(4-chlorophenyl)-S-methyl-N-(4-tosyl)sulfilimine