N-benzoyl-2-(carbethoxymethyl)-5-methoxy-p-benzoquinone imine dimethyl ketal

Base Information

Chemical Name:N-benzoyl-2-(carbethoxymethyl)-5-methoxy-p-benzoquinone imine dimethyl ketal
CAS No.:117559-83-8
Molecular Formula:C₂₀H₂₃NO₆
Molecular Weight:373.406
Hs Code.:

Synonyms:N-benzoyl-2-(carbethoxymethyl)-5-methoxy-p-benzoquinone imine dimethyl ketal

Suppliers and Price of N-benzoyl-2-(carbethoxymethyl)-5-methoxy-p-benzoquinone imine dimethyl ketal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of N-benzoyl-2-(carbethoxymethyl)-5-methoxy-p-benzoquinone imine dimethyl ketal

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of N-benzoyl-2-(carbethoxymethyl)-5-methoxy-p-benzoquinone imine dimethyl ketal

There total 6 articles about N-benzoyl-2-(carbethoxymethyl)-5-methoxy-p-benzoquinone imine dimethyl ketal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 67-56-1
methanol

: 117559-76-9
ethyl 2-benzamido-4,5-dimethoxyphenylacetate

: 117559-83-8
N-benzoyl-2-(carbethoxymethyl)-5-methoxy-p-benzoquinone imine dimethyl ketal

Guidance literature:: With 2,6-dimethylpyridine; lithium perchlorate; at 0 ℃; for 1h; anodic oxidation: Pt electrode, 0.1 A;
DOI:10.1021/jo00262a018

Reference yield:

: 93-40-3
(3,4-Dimethoxyphenyl)acetic acid

: 117559-83-8
N-benzoyl-2-(carbethoxymethyl)-5-methoxy-p-benzoquinone imine dimethyl ketal

Guidance literature:: Multi-step reaction with 6 steps

1: thionyl chloride / 5 h / Ambient temperature

2: 1 h

3: HNO₃ / acetic acid / 1 h / 0 °C

4: H₂ / 5percent Pd/C / tetrahydrofuran / 10 h / 3620.04 Torr

5: NEt₃ / tetrahydrofuran / 4 h

6: 97 percent / LiClO₄, 2,6-lutidine / 1 h / 0 °C / anodic oxidation: Pt electrode, 0.1 A

With 2,6-dimethylpyridine; thionyl chloride; hydrogen; nitric acid; lithium perchlorate; triethylamine; palladium on activated charcoal; In tetrahydrofuran; acetic acid;
DOI:10.1021/jo00262a018

Reference yield:

: 18066-68-7
ethyl 3,4-dimethoxyphenylacetate

: 117559-83-8
N-benzoyl-2-(carbethoxymethyl)-5-methoxy-p-benzoquinone imine dimethyl ketal

Guidance literature:: Multi-step reaction with 4 steps

1: HNO₃ / acetic acid / 1 h / 0 °C

2: H₂ / 5percent Pd/C / tetrahydrofuran / 10 h / 3620.04 Torr

3: NEt₃ / tetrahydrofuran / 4 h

4: 97 percent / LiClO₄, 2,6-lutidine / 1 h / 0 °C / anodic oxidation: Pt electrode, 0.1 A

With 2,6-dimethylpyridine; hydrogen; nitric acid; lithium perchlorate; triethylamine; palladium on activated charcoal; In tetrahydrofuran; acetic acid;
DOI:10.1021/jo00262a018