phenyl 6-azido-6-deoxy-3,4-O-[(2S,3S)-2,3-dimethoxybutane-2,3-diyl]-2-O-(trimethylsilyl)-1-thio-α-D-mannopyranoside

Base Information

Chemical Name:phenyl 6-azido-6-deoxy-3,4-O-[(2S,3S)-2,3-dimethoxybutane-2,3-diyl]-2-O-(trimethylsilyl)-1-thio-α-D-mannopyranoside
CAS No.:1407159-10-7
Molecular Formula:C₂₁H₃₃N₃O₆SSi
Molecular Weight:483.661
Hs Code.:

Synonyms:phenyl 6-azido-6-deoxy-3,4-O-[(2S,3S)-2,3-dimethoxybutane-2,3-diyl]-2-O-(trimethylsilyl)-1-thio-α-D-mannopyranoside

Suppliers and Price of phenyl 6-azido-6-deoxy-3,4-O-[(2S,3S)-2,3-dimethoxybutane-2,3-diyl]-2-O-(trimethylsilyl)-1-thio-α-D-mannopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of phenyl 6-azido-6-deoxy-3,4-O-[(2S,3S)-2,3-dimethoxybutane-2,3-diyl]-2-O-(trimethylsilyl)-1-thio-α-D-mannopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of phenyl 6-azido-6-deoxy-3,4-O-[(2S,3S)-2,3-dimethoxybutane-2,3-diyl]-2-O-(trimethylsilyl)-1-thio-α-D-mannopyranoside

There total 1 articles about phenyl 6-azido-6-deoxy-3,4-O-[(2S,3S)-2,3-dimethoxybutane-2,3-diyl]-2-O-(trimethylsilyl)-1-thio-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 876862-55-4
phenyl 6-azido-6-deoxy-3,4-O-(2',3'-dimethoxybutane-2',3'-diyl)-1-thio-α-D-mannopyranoside

: 75-77-4
chloro-trimethyl-silane

: 1407159-10-7
phenyl 6-azido-6-deoxy-3,4-O-[(2S,3S)-2,3-dimethoxybutane-2,3-diyl]-2-O-(trimethylsilyl)-1-thio-α-D-mannopyranoside

Guidance literature:: With lithium hexamethyldisilazane; In acetonitrile; for 24h; stereoselective reaction; Molecular sieve; Inert atmosphere;
DOI:10.1002/ejoc.201200084

Reference yield: 75.0%

: 21209-51-8
N-benzyloxycarbonyl-L-serine benzyl ester

: 1407159-10-7
phenyl 6-azido-6-deoxy-3,4-O-[(2S,3S)-2,3-dimethoxybutane-2,3-diyl]-2-O-(trimethylsilyl)-1-thio-α-D-mannopyranoside

: 1407159-26-5
3-O-{6-azido-6-deoxy-3,4-O-[(2S,3S)-2,3-dimethoxybutane-2,3-diyl]-2-O-(trimethylsilyl)-α-D-mannopyranosyl}-N-(benzyloxycarbonyl)-L-serine benzyl ester

Guidance literature:: phenyl 6-azido-6-deoxy-3,4-O-[(2S,3S)-2,3-dimethoxybutane-2,3-diyl]-2-O-(trimethylsilyl)-1-thio-α-D-mannopyranoside; With 1-benzenesulfinyl piperidine; trifluoromethylsulfonic anhydride; 2,4,6-tri-tert-butylpyrimidine; In dichloromethane; at -60 - 20 ℃; Inert atmosphere; Molecular sieve;

N-benzyloxycarbonyl-L-serine benzyl ester; In dichloromethane; at -20 ℃; for 0.333333h; optical yield given as %ee; Inert atmosphere; Molecular sieve;
DOI:10.1002/ejoc.201200084

Reference yield: 75.0%

: 82509-76-0
dibenzyl (3aS,4R,5S,7R,7aS)-4-hydroxyhexahydrospiro[benzo[d][1,3]dioxole-2,1'-cyclohexane]-5,7-diyldicarbamate

: 1407159-10-7
phenyl 6-azido-6-deoxy-3,4-O-[(2S,3S)-2,3-dimethoxybutane-2,3-diyl]-2-O-(trimethylsilyl)-1-thio-α-D-mannopyranoside

: 1407159-12-9
4-O-{6-azido-6-deoxy-3,4-O-[(2S,3S)-2,3-dimethoxybutane-2,3-diyl]-2-O-(trimethylsilyl)-α-D-mannopyranosyl}-1,3-bis[N-(benzyloxycarbonyl)]-5,6-O-cyclohexylidene-2-deoxystreptamine

Guidance literature:: With 1-benzenesulfinyl piperidine; trifluoromethylsulfonic anhydride; 2,4,6-tri-tert-butylpyrimidine; In dichloromethane; at -60 - 20 ℃; for 0.333333h; stereoselective reaction; Inert atmosphere; Molecular sieve;
DOI:10.1002/ejoc.201200084