2,3,4,6-tetra-O-benzyl-1-O-[N-allyl-thiocarbamoyl]-D-glucopyranose

Base Information

• Chemical Name: 2,3,4,6-tetra-O-benzyl-1-O-[N-allyl-thiocarbamoyl]-D-glucopyranose
• CAS No.: 371766-59-5
• Molecular Formula: C₃₈H₄₁NO₆S
• Molecular Weight: 639.813
• Mol file: 371766-59-5.mol

Synonyms:2,3,4,6-tetra-O-benzyl-1-O-[N-allyl-thiocarbamoyl]-D-glucopyranose

Chemical Property of 2,3,4,6-tetra-O-benzyl-1-O-[N-allyl-thiocarbamoyl]-D-glucopyranose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3,4,6-tetra-O-benzyl-1-O-[N-allyl-thiocarbamoyl]-D-glucopyranose

There total 1 articles about 2,3,4,6-tetra-O-benzyl-1-O-[N-allyl-thiocarbamoyl]-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3,4,6-Tetra-O-benzyl-D-glucopyranose (4291-69-4,6386-24-9,6564-72-3,59531-24-7,69257-52-9,78184-89-1,78609-16-2,78609-17-3,78609-18-4,96553-53-6,104111-61-7,131347-08-5,4132-28-9) + N-allyl isothiocyanate (57-06-7,58391-87-0) → 2,3,4,6-tetra-O-benzyl-1-O-[N-allyl-thiocarbamoyl]-D-glucopyranose (371766-59-5)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; potassium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; 4 A MS; In toluene; for 4h;

DOI:10.1016/j.carres.2005.07.010

Reference yield: 97.0%

2,3,4,6-tetra-O-benzyl-1-O-[N-allyl-thiocarbamoyl]-D-glucopyranose (371766-59-5) + methanol (67-56-1) → methyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside (3879-79-6,17791-37-6,19488-61-0,53008-63-2,61330-62-9,69237-94-1,69237-95-2,71526-33-5,83462-67-3,84799-77-9,103421-29-0,103421-30-3,139241-42-2)

Guidance literature:

With bromine; sodium hydrogencarbonate; lithium fluoride; In 1,2-dichloro-ethane; N,N-dimethyl-formamide; at -25 ℃; for 0.166667h;

Reference yield: 96.5%

2,3,4,6-tetra-O-benzyl-1-O-[N-allyl-thiocarbamoyl]-D-glucopyranose (371766-59-5) + tert-butyl alcohol (75-65-0) → tert-butyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside (78153-80-7,128745-66-4,128745-67-5,136984-90-2,136984-93-5,67525-69-3)

Guidance literature:

With bromine; sodium hydrogencarbonate; lithium fluoride; In 1,2-dichloro-ethane; N,N-dimethyl-formamide; at -25 ℃; for 0.166667h;

upstream raw materials:

2,3,4,6-Tetra-O-benzyl-D-glucopyranose

N-allyl isothiocyanate

Downstream raw materials:

1,2-anhydro-3-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-sn-glycerol

2,3-anhydro-3-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-sn-glycerol

methyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside

n-dodecyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside