2,6-di-t-butyl-4-methylphenyl cis-(1R,2S)-2-phenylcyclopropane-1-carboxylate

Base Information

Chemical Name:2,6-di-t-butyl-4-methylphenyl cis-(1R,2S)-2-phenylcyclopropane-1-carboxylate
CAS No.:131899-85-9
Molecular Formula:C₂₅H₃₂O₂
Molecular Weight:364.528
Hs Code.:

Synonyms:2,6-di-t-butyl-4-methylphenyl cis-(1R,2S)-2-phenylcyclopropane-1-carboxylate

Suppliers and Price of 2,6-di-t-butyl-4-methylphenyl cis-(1R,2S)-2-phenylcyclopropane-1-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,6-di-t-butyl-4-methylphenyl cis-(1R,2S)-2-phenylcyclopropane-1-carboxylate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,6-di-t-butyl-4-methylphenyl cis-(1R,2S)-2-phenylcyclopropane-1-carboxylate

There total 5 articles about 2,6-di-t-butyl-4-methylphenyl cis-(1R,2S)-2-phenylcyclopropane-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6
styrene

: 125640-92-8
2,6-di-tert-butyl-4-methylphenyl diazoacetate

: 108546-83-4,125641-27-2,125641-28-3,131899-82-6,131899-85-9
2,6-di-tert-butyl-4-methylphenyl trans-2-phenylcyclopropanecarboxylate

Guidance literature:: Rh₂(acam)4; In dichloromethane; for 2h; Heating;

Reference yield:

: 128-37-0
2,6-di-tert-butyl-4-methyl-phenol

: 108546-83-4,125641-27-2,125641-28-3,131899-82-6,131899-85-9
2,6-di-tert-butyl-4-methylphenyl trans-2-phenylcyclopropanecarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 76 percent / triethylamine, methanesulfonyl azide / acetonitrile / 1.) reflux, 2.) RT, 7 h

2: 5percent aq. KOH / acetonitrile / 24 h / Ambient temperature

3: 86 percent / Rh₂(acam)4 / CH₂Cl₂ / 2 h / Heating

With potassium hydroxide; triethylamine; Methanesulfonyl azide; Rh₂(acam)4; In dichloromethane; acetonitrile;

Reference yield:

: 125641-00-1
2,6-Bis(1,1-dimethylethyl)-4-methylphenyl 2-diazo-3-butenoate

: 108546-83-4,125641-27-2,125641-28-3,131899-82-6,131899-85-9
2,6-di-tert-butyl-4-methylphenyl trans-2-phenylcyclopropanecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 5percent aq. KOH / acetonitrile / 24 h / Ambient temperature

2: 86 percent / Rh₂(acam)4 / CH₂Cl₂ / 2 h / Heating

With potassium hydroxide; Rh₂(acam)4; In dichloromethane; acetonitrile;