trifluoromethanesulfonic acid [2-(diethoxyphosphoryl)-3,5-diisopropoxy-phenyl]ester

Base Information

Chemical Name:trifluoromethanesulfonic acid [2-(diethoxyphosphoryl)-3,5-diisopropoxy-phenyl]ester
CAS No.:859103-24-5
Molecular Formula:C₁₇H₂₆F₃O₈PS
Molecular Weight:478.424
Hs Code.:

Synonyms:trifluoromethanesulfonic acid [2-(diethoxyphosphoryl)-3,5-diisopropoxy-phenyl]ester

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Chemical Property of trifluoromethanesulfonic acid [2-(diethoxyphosphoryl)-3,5-diisopropoxy-phenyl]ester

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Technology Process of trifluoromethanesulfonic acid [2-(diethoxyphosphoryl)-3,5-diisopropoxy-phenyl]ester

There total 4 articles about trifluoromethanesulfonic acid [2-(diethoxyphosphoryl)-3,5-diisopropoxy-phenyl]ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 859103-20-1
(2-hydroxy-4,6-diisopropoxy-phenyl)phosphonic acid diethyl ester

: 98611-89-3
N-phenylbis(trifluoromethanesulfonyl)amine

: 859103-24-5
trifluoromethanesulfonic acid [2-(diethoxyphosphoryl)-3,5-diisopropoxy-phenyl]ester

Guidance literature:: (2-hydroxy-4,6-diisopropoxy-phenyl)phosphonic acid diethyl ester; With (1,4,7,10-tetraoxacyclododecane); sodium hydride; In tetrahydrofuran; at 20 ℃; for 0.166667h;

N,N-diphenyltrifluoromethanesulfonamide; In tetrahydrofuran;
DOI:10.1016/j.tetlet.2005.04.104

Reference yield:

: 859103-16-5
phosphoric acid (3,5-di-isopropoxy-phenyl)ester diethyl ester

: 859103-24-5
trifluoromethanesulfonic acid [2-(diethoxyphosphoryl)-3,5-diisopropoxy-phenyl]ester

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / LDA / tetrahydrofuran / -78 °C

2: NaH; 12-crown-4 / tetrahydrofuran

With (1,4,7,10-tetraoxacyclododecane); sodium hydride; lithium diisopropyl amide; In tetrahydrofuran; 1: phospho-Fries rearrangement;
DOI:10.1016/j.tet.2007.07.042

Reference yield:

: 108-73-6
3,5-dihydroxyphenol

: 859103-24-5
trifluoromethanesulfonic acid [2-(diethoxyphosphoryl)-3,5-diisopropoxy-phenyl]ester

Guidance literature:: Multi-step reaction with 4 steps

1: K₂CO₃; KI / dimethylformamide / 72 h / 50 °C

2: CCl₄ / acetonitrile

3: 92 percent / LDA / tetrahydrofuran / -78 °C

4: NaH; 12-crown-4 / tetrahydrofuran

With tetrachloromethane; (1,4,7,10-tetraoxacyclododecane); sodium hydride; potassium carbonate; potassium iodide; lithium diisopropyl amide; In tetrahydrofuran; N,N-dimethyl-formamide; acetonitrile; 3: phospho-Fries rearrangement;
DOI:10.1016/j.tet.2007.07.042